401439
高氯酸锌 六水合物
别名:
Perchloric acid zinc hydrate
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关于此项目
线性分子式:
Zn(ClO4)2·6H2O
化学文摘社编号:
分子量:
372.38
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
237-122-0
MDL number:
Form:
crystals and lumps
form
crystals and lumps
Quality Level
reaction suitability
core: zinc, reagent type: oxidant
SMILES string
O.O.O.O.O.O.[Zn++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
InChI
1S/2ClHO4.6H2O.Zn/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);6*1H2;/q;;;;;;;;+2/p-2
InChI key
PADPILQDYPIHQQ-UHFFFAOYSA-L
General description
高氯酸锌六水合物是锌的六水盐类，在各种有机转化中广泛用作氧化剂和催化剂。也可用于二次电池领域。
Application
高氯酸锌六水合物可作为以下反应的催化剂：
- 缺电子 酚类、空间位阻醇类和胺类的乙酰化。
- 环氧化合物与硫醇开环反应合成2-羟基硫化物。
- 羧酸和醇的无‐溶剂缩合。
- 水基锌电池的电解质。
- 强荧光ZnSe量子点的前体。
signalword
Danger
hcodes
Hazard Classifications
Ox. Sol. 2 - Skin Corr. 1B
存储类别
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
商品
Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.
Zinc perchlorate hexahydrate [Zn(ClO4)2?6H2O] as acylation catalyst for poor nucleophilic phenols, alcohols and amines: Scope and limitations
Shivani, et al.
J. Mol. Catal. A: Chem., 264, 208-213 (2007)
Highly Efficient Solvent-Free Condensation of Carboxylic Acids with Alcohols Catalysed by Zinc Perchlorate Hexahydrate, Zn(ClO4)2?6 H2O
G Bartoli, et al.
Advanced Synthesis & Catalysis, 347, 33-38 (2005)
Photo-assisted synthesis of highly fluorescent ZnSe(S) quantum dots in aqueous solution
Guo-Yu Lan, et al.
Journal of Materials Chemistry, 17, 2661-2666 (2007)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 401439-100G | 04061831985474 |
| 401439-500G | 04061831985481 |