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403083

1,3-二溴金刚烷

Name: 1,3-二溴金刚烷
Brand: ALDRICH

99%

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关于此项目

经验公式（希尔记法）:

C₁₀H₁₄Br₂

化学文摘社编号:

876-53-9

分子量:

294.03

NACRES:

NA.22

PubChem Substance ID:

24865163

UNSPSC Code:

12352100

MDL number:

MFCD00077218

Assay:

99%

Form:

powder

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属性

Quality Level

100

assay

99%

form

powder

mp

108-110 °C (lit.)

functional group

bromo

SMILES string

Br[C@]12C[C@@H]3C[C@H](C1)C[C@@](Br)(C3)C2

InChI

1S/C10H14Br2/c11-9-2-7-1-8(4-9)5-10(12,3-7)6-9/h7-8H,1-6H2/t7-,8+,9+,10-

InChI key

HLWZKLMEOVIWRK-FIRGSJFUSA-N

说明

General description

1,3-Dibromoadamantane is reported to react with diphenylphosphide ions (Ph₂P^-) under photostimulation by the S_RN1 mechanism. The viscosity-dependent retarding effect of 1,3-dibromoadamantane in highly viscous polymeric chlorotrifluoroethene has been studied by 13C NMR relaxation measurements. Preparation of 1,3-dibromoadamantane via dibromination of adamantine has been reported.

Application

1,3-Dibromoadamantane may be used in the preparation of 1,3-bis(phenyldimethylsilyl)adamantine.

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

法规信息

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Preparation of 1-silyl-and 1, 3-disilyl-adamantanes.

Pai Y-M, et al.

Journal of Organometallic Chemistry, 270(3), 271-275 (1984)

Reactions of 1, 3-dihaloadamantanes with diphenylphosphide ions by the SRN1 mechanism. Competition between intermolecular and intramolecular electron transfer reactions.

Lukach AE, et al.

Journal of Physical Organic Chemistry, 7(11), 610-614 (1994)

Selective dibromination of adamantane.

Talaty ER, et al.

J. Chem. Soc. Sect. C, 1902-1903 (1968)

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货号	GTIN
403083-1G	04061831986464