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Merck
CN

404586

Sigma-Aldrich

芥子醇

technical grade, 80%

别名:

4-羟基-3,5-二甲氧基肉桂醇

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关于此项目

线性分子式:
HOC6H2(OCH3)2CH=CHCH2OH
化学文摘社编号:
分子量:
210.23
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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等级

technical grade

质量水平

方案

80%

表单

solid

mp

61-65 °C (lit.)

官能团

hydroxyl

储存温度

2-8°C

SMILES字符串

COc1cc(\C=C\CO)cc(OC)c1O

InChI

1S/C11H14O4/c1-14-9-6-8(4-3-5-12)7-10(15-2)11(9)13/h3-4,6-7,12-13H,5H2,1-2H3/b4-3+

InChI key

LZFOPEXOUVTGJS-ONEGZZNKSA-N

一般描述

芥子醇是一种单体低聚物,是木质素的主要单体。已对其抗炎和抗伤害感受活性进行了评价。参与木质素生物合成的初始阶段。已有芥子醇与芥子醇 -对 -羟基苯甲酸酯的偶联反应相关报告。已研究使用二异丁基氢化铝作为还原剂,通过选择性地 1,2-还原相应的肉桂酸酯来制备芥子醇。

应用

芥子醇可用于制备木质素,木质素是一种高度稳定的生物聚合物。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jun Shigeto et al.
Journal of plant research, 130(1), 203-210 (2016-11-27)
Most of the known 4-coumarate:coenzyme A ligase (4CL) isoforms lack CoA-ligation activity for sinapic acid. Therefore, there is some doubt as to whether sinapic acid contributes to sinapyl alcohol biosynthesis. In this study, we characterized the enzyme activity of a
A possible mechanism for the oxidation of sinapyl alcohol by peroxidase-dependent reactions in the apoplast: enhancement of the oxidation by hydroxycinnamic acids and components of the apoplast.
Takahama U, et al.
Plant Physiology, 37(4), 499-504 (1996)
Zhen Fang et al.
Bioresource technology, 99(9), 3424-3430 (2007-09-21)
Decomposition of organosolve lignin in water/phenol solutions was studied in a 50 nL micro-reactor coupled with optical, Raman and infrared microscopies at temperatures up to 600 degrees C and water densities up to 1165 kg/m3. It was found that when
Fachuang Lu et al.
Organic & biomolecular chemistry, 2(20), 2888-2890 (2004-10-14)
Cross-coupling of sinapyl p-hydroxybenzoate and sinapyl alcohol produces an 8-8-cross-coupled product that is also detected in lignifying poplar tissues, implicating sinapyl p-hydroxybenzoate as a lignin precursor.
Jongwon Choi et al.
Planta medica, 70(11), 1027-1032 (2004-11-19)
In the present study, syringin, isolated by activity-guided fractionation of the ethyl acetate (EtOAc) extracts of the stem bark of Magnolia sieboldii, and sinapyl alcohol, the hydrolysate of syringin, were evaluated for anti-inflammatory and antinociceptive activities. Sinapyl alcohol (20, 30

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