方案
99%
mp
114-116 °C (lit.)
SMILES字符串
O=C1N(Cc2ccccc2)C(=O)c3ccccc13
InChI
1S/C15H11NO2/c17-14-12-8-4-5-9-13(12)15(18)16(14)10-11-6-2-1-3-7-11/h1-9H,10H2
InChI key
WITXFYCLPDFRNM-UHFFFAOYSA-N
一般描述
N-Benzylphthalimide (NBPT), also known as 2-benzylisoindoline-1,3-dione, is an N-substituted phthalimide. It has been prepared by reacting phthalic anhydride with benzyl amine in glacial acetic acid. Vibrational spectra of NBPT has been recorded and assigned. NBPT is a roof-shaped molecule with a planar cyclic imide and a phenyl ring connected by a methylene group. Crystal structure of N-benzylphthalimide has parallel layers of phthalimides stack along the a axis.
应用
N-Benzylphthalimide may be used in the following syntheses:
- 2-benzyl-1,1,3,3-tetraphenylisoindoline
- tailor-made highly fluorous porphyrin derivatives
- N-benzylisoindole
Highly fluorous porphyrins as model compounds for molecule interferometry.
Tuxen J, et al.
European Journal of Organic Chemistry, 25, 4823-4833 (2011)
Impact of molecular size on electron spin relaxation rates of nitroxyl radicals in glassy solvents between 100 and 300 K.
Sato HIDEO, et al.
Molecular Physics, 105(15-16), 2137-2151 (2007)
N-benzylphthalimide.
Warzecha K-D, et al.
Acta Crystallographica Section E, Structure Reports Online, 62(6), 2367-2368 (2006)
The direct conversion of phthalimides to isoindoles.
Garmaise DL and Ryan A.
Journal of Heterocyclic Chemistry, 7(2), 413-413 (1970)
Vibrational assignment of N-benzylphthalimide and 15N-benzylphthalimide.
Kolev T and Juchnovski I.
Journal of Molecular Structure, 349, 377-380 (1995)
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