405000
(-)-2,2′-异亚丙基双[(4S)-4-苯基-2-噁唑啉]
97%
别名:
(S,S)-2,2-双(4-苯基-2-噁唑啉-2-基)丙烷, (S,S)-2,2′-异亚丙基双(4-苯基-2-噁唑啉)
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关于此项目
产品名称
(-)-2,2′-异亚丙基双[(4S)-4-苯基-2-噁唑啉], 97%
InChI
1S/C21H22N2O2/c1-21(2,19-22-17(13-24-19)15-9-5-3-6-10-15)20-23-18(14-25-20)16-11-7-4-8-12-16/h3-12,17-18H,13-14H2,1-2H3/t17-,18-/m1/s1
SMILES string
CC(C)(C1=N[C@H](CO1)c2ccccc2)C3=N[C@H](CO3)c4ccccc4
InChI key
JTNVCJCSECAMLD-QZTJIDSGSA-N
assay
97%
optical activity
[α]20/D −160°, c = 1 in ethanol
bp
193 °C/0.03 mmHg (lit.)
mp
37-41 °C (lit.)
density
1 g/mL at 25 °C (lit.)
functional group
ether
phenyl
storage temp.
−20°C
Quality Level
Application
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
商品
BOX ligand complex enhances catalytic enantioselective aziridination of styrene, with phenyl substituents proving superior over t-Bu groups.
使用络合Cu(I)OTf的BOX配体进行不对称催化苯乙烯合成氮杂环丙烷的反应，BOX配体带苯基取代基的优于具有位阻需求的叔丁(t-Bu)基团。
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