405868
4′-氯-2,2′:6′,2′′-三联吡啶
99%
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关于此项目
经验公式（希尔记法）:
C15H10ClN3
化学文摘社编号:
分子量:
267.71
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
99%
InChI
1S/C15H10ClN3/c16-11-9-14(12-5-1-3-7-17-12)19-15(10-11)13-6-2-4-8-18-13/h1-10H
SMILES string
Clc1cc(nc(c1)-c2ccccn2)-c3ccccn3
InChI key
AHEMFMCEBIJRMU-UHFFFAOYSA-N
assay
99%
greener alternative product score
old score: 51
new score: 35
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Greener Alternative Product
mp
148-150 °C (lit.)
functional group
chloro
greener alternative category
Quality Level
General description
4′-氯-2,2′:6′,2′-三联吡啶 (4′-Cltpy,Cltpy,Cl-terpy) 是一种三齿配体，含有一个三联吡啶 (tpy) 位点，Cl 位点在 4-位。它通过这两个位点与各种金属离子配位形成不同的配位聚合物。晶体结构研究表明，Cltpy 的三吡啶单元为反式、反式构象。分子沿 b 轴自行组装成堆叠柱，平面间距离为 3.51Å。 与 α,ω-双羟基-官能化的聚环氧丙烷发生 Williamson 型醚反应。它与 α-羟基-ω-羧基官能化的聚氧化乙烯发生 Williamson 型反应，得到单吡啶端基遥爪。
我们竭诚为您带来满足绿色替代产品四大类别要求的替代产品。本品属于重新设计产品类别，在“防止废弃物”、“原子经济性”、“危险性较小的化学合成”、“更安全的溶剂和助剂”和“使用可再生原料”绿色化学原则方面取得了重大进步。 点击此处查看其DOZN记分卡。
Application
4′-氯-2,2′:6′,2′′-三吡啶可用于以下制备过程：
- 单吡啶和双吡啶
- 双羟基功能化的三吡啶镉 (II) 配合物和富勒烯衍生物
- 4-官能化 2,2″:6″,2″-三吡啶，新型超分子结构的构建模块，如双螺旋化合物、树枝状聚合物、胶束和金属超分子聚合物
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
New 4'-Functionalized 2, 2': 6', 2''-Terpyridines for Applications in Macromolecular Chemistry and Nanoscience.
Andres PR, et al.
European Journal of Organic Chemistry, 2003(19), 3769-3776 (2003)
Access to supramolecular polymers: Large scale synthesis of 4'-chloro-2, 2': 6', 2''-terpyridine and an application to poly (propylene oxide) telechelics.
Schubert US, et al.
Designed Monomers and Polymers, 5(2-3), 211-221 (2002)
Functionalized oligomers and copolymers with metal complexing segments: a simple and high yield entry towards 2, 2': 6', 2 ?-terpyridine monofunctionalized telechelics.
Schubert US and Eschbaumer C.
Macromolecular Symposia, 163(1) (2001)
Synthesis, Characterization, Crystal Structure, and Biological Studies of a Cadmium (II) Complex with a Tridentate Ligand 4'-Chloro-2,2':6',2''-Terpyridine.
Saghatforoush LA, et al.
Bioinorganic Chemistry and Applications, 2011 (2011)
4'-Chloro-2, 2': 6', 2''-terpyridine.
Beves JE, et al.
Acta Crystallographica Section E, Structure Reports Online, 62(6), o2497-o2498 (2006)
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