405965
2,2′-亚甲基双[(4S)-4-叔丁基-2-噁唑啉]
99%
别名:
(S,S)-2,2′-亚甲基双(4-叔丁基-2-噁唑啉)
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关于此项目
经验公式（希尔记法）:
C15H26N2O2
化学文摘社编号:
分子量:
266.38
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4190673
Quality Level
assay
99%
optical activity
[α]20/D −118°, c = 0.5 in chloroform
mp
51-53 °C (lit.)
functional group
ether
SMILES string
CC(C)(C)[C@H]1COC(CC2=N[C@H](CO2)C(C)(C)C)=N1
InChI
1S/C15H26N2O2/c1-14(2,3)10-8-18-12(16-10)7-13-17-11(9-19-13)15(4,5)6/h10-11H,7-9H2,1-6H3/t10-,11-/m1/s1
InChI key
WCCCBUXURHZPQL-GHMZBOCLSA-N
Application
2，2′-亚甲基双[（4S）-4-叔丁基-2-恶唑啉]（BOX配体）可以用作C2对称配体进行对映选择性不对称催化。由于恶唑啉氮对各种金属的强亲和力，它很容易形成双齿配位配合物。
对映选择性催化反应的 C2 对称配体由于噁唑啉氮具有对各种金属的强亲合性，因此可容易地形成双齿配位络合物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
商品
BOX ligand complex enhances catalytic enantioselective aziridination of styrene, with phenyl substituents proving superior over t-Bu groups.
使用络合Cu(I)OTf的BOX配体进行不对称催化苯乙烯合成氮杂环丙烷的反应，BOX配体带苯基取代基的优于具有位阻需求的叔丁(t-Bu)基团。
Selective oxidation of alkenes and alkynes catalyzed by copper complexes
Alvarez LX, et al.
Applied Catalysis A: General, 325(2), 303-308 (2007)
C 2-Symmetric bis (oxazolinato) lanthanide catalysts for enantioselective intramolecular hydroamination/cyclization
Hong S, et al.
Journal of the American Chemical Society, 125(48), 14768-14783 (2003)
Heterogeneous bisoxazoline/copper complex: A green catalyst for the enantioselective reaction of nitromethane with substituted benzaldehydes
Maggi R, et al.
European Journal of Organic Chemistry, 2011(28), 5551-5554 (2011)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 405965-500MG | 04061832985794 |