406023
二乙基锌 溶液
1.0 M in heptane
别名:
Zincdiethyl
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关于此项目
线性分子式:
(C2H5)2Zn
化学文摘社编号:
分子量:
123.51
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587207
产品名称
二乙基锌 溶液, 1.0 M in heptane
InChI
1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
SMILES string
CC[Zn]CC
InChI key
HQWPLXHWEZZGKY-UHFFFAOYSA-N
form
liquid
concentration
1.0 M in heptane
bp
98 °C
density
0.74 g/mL at 25 °C
Quality Level
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Application
二乙基锌溶液可用于合成：
- 双（吡啶基吡咯基）锌发光配合物。
- 通用构件块，5-（酮芳基）噻唑。
- 具有高发光性能的 ZnxCd1-xSe 纳米晶体。
signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Central nervous system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
12.2 °F - closed cup
flash_point_c
-11 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Pyridylpyrrolides as alternatives to cyclometalated phenylpyridine ligands: synthesis and characterization of luminescent zinc and boron pyridylpyrrolide complexes.
Klappa JJ, et al.
Dalton Transactions, 883-891 (2004)
Composition-Tunable ZnxCd1-xSe nanocrystals with high luminescence and stability.
Xinhua Z, et al.
Journal of the American Chemical Society, 125(28), 8589-8594 (2003)
Practical synthesis of a highly functionalized thiazole ketone.
Frey LF, et al.
Tetrahedron, 59(33), 6363-6373 (2003)
Takuji Hirose et al.
The Journal of organic chemistry, 76(13), 5413-5428 (2011-05-20)
Twenty chiral 1,3-amino sulfonamides of two classes (2a-i and 3a-k) have been prepared from (-)-cis-2-benzamidocyclohexanecarboxylic acid (1) and studied as ligands for catalytic enantioselective addition of Et(2)Zn to a variety of aromatic and aliphatic aldehydes. The ligands 2 and 3
Hong Li et al.
The Journal of organic chemistry, 73(18), 7398-7401 (2008-08-15)
Direct asymmetric aldol reaction of aryl ketones with aryl aldehydes catalyzed by chiral metal complex is reported for the first time herein. Two novel semicrown chiral ligands 1a and 1b were synthesized from (S)- and (R)-BINOL, respectively, and then employed
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