406961
(+)-2,2′-异亚丙基双[(4R)-4-苯基-2-噁唑啉]
97%
别名:
(R,R)-2,2′-双(4-苯基-2-噁唑啉-2-基)丙烷, (R,R)-2,2′-异亚丙基双(4-苯基-2-噁唑啉)
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关于此项目
经验公式（希尔记法）:
C21H22N2O2
化学文摘社编号:
分子量:
334.41
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4266906
Quality Segment
assay
97%
form
solid
optical activity
[α]20/D +160°, c = 1 in ethanol
mp
56-58 °C (lit.)
functional group
ether, phenyl
storage temp.
−20°C
SMILES string
CC(C)(C1=N[C@@H](CO1)c2ccccc2)C3=N[C@@H](CO3)c4ccccc4
InChI
1S/C21H22N2O2/c1-21(2,19-22-17(13-24-19)15-9-5-3-6-10-15)20-23-18(14-25-20)16-11-7-4-8-12-16/h3-12,17-18H,13-14H2,1-2H3/t17-,18-/m0/s1
InChI key
JTNVCJCSECAMLD-ROUUACIJSA-N
Application
不对称催化作用的 C2 对称配体。由于噁唑啉氮具有对各种金属的强亲合性，因此容易形成双齿配位络合物。
(+)-2,2′-Isopropylidenebis[(4R)-4-phenyl-2-oxazoline] in the presence of copper iodide, can catalyze the asymmetric cyclopropanation reaction of phenyliodonium ylides with alkenes to form cyclopropane α-amino acid esters.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges