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Merck
CN

407097

1-溴-2,4,6-三叔丁基苯

97%

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关于此项目

线性分子式:
[(CH3)3C]3C6H2Br
化学文摘社编号:
分子量:
325.33
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1913257
Assay:
97%
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Quality Segment

assay

97%

mp

168-173 °C (lit.)

functional group

bromo

SMILES string

CC(C)(C)c1cc(c(Br)c(c1)C(C)(C)C)C(C)(C)C

InChI

1S/C18H29Br/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,1-9H3

InChI key

JOKZWHPYNRDCOA-UHFFFAOYSA-N

General description

1-Bromo-2,4,6-tri-tert-butylbenzene (2,4,6-tri-tert-butylbromobenzene) is a hindered aryl bromide. 1-Bromo-2,4,6-tri-tert-butylbenzene on reaction with phenylboronic acid yields α,α-dimethyl-β-phenyl hydrostyrene.

Application

1-Bromo-2,4,6-tri-tert-butylbenzene was used in the synthesis of bulky biarylphosphine ligand. This ligand was reported to participate in the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions. It was used to investigate the effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates. It may be used to form α,α-dimethyl-β-phenyl hydrostyrene by reacting with phenylboronic acid.


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警示词

Warning

危险代码

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

存储类别

11 - Combustible Solids

怎么回事?

WGK 3

闪点 (F)

Not applicable

闪点 (°C)

Not applicable

PPE(个人防护设备)

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

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