407879
2,4,6-三甲氧基-1,3,5-三嗪
98%
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关于此项目
经验公式（希尔记法）:
C6H9N3O3
化学文摘社编号:
分子量:
171.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
212-896-2
MDL number:
产品名称
2,4,6-三甲氧基-1,3,5-三嗪, 98%
InChI key
DFUGJTBMQKRCPI-UHFFFAOYSA-N
InChI
1S/C6H9N3O3/c1-10-4-7-5(11-2)9-6(8-4)12-3/h1-3H3
SMILES string
COc1nc(OC)nc(OC)n1
assay
98%
mp
135-137 °C (lit.)
Quality Level
Application
2,4,6-Trimethoxy-1,3,5-triazine was used to investigate the molecularly imprinted solid phase extraction (MISPE) for the isolation of melamine (ML) in food products.
General description
2,4,6-Trimethoxy-1,3,5-triazine (TMT) is a triazine derivative. It exists in three different polymorphic forms: α-, β- and γ-. 2,4,6-Trimethoxy-1,3,5-triazine molecules are planar in all the three polymorphs. Polymorphic forms differ in the mode of packing of the molecules in the crystal. Kinetics and mechanism of the reaction of radiolytically produced hydrated electron with TMT using pulse and steady-state radiolysis techniques has been studied. TMT undergoes methyl transfer in the melt and in the solid-state, to afford, 2,4,6-trioxo-1,3,5-trimethylazine.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Rani Varghese et al.
Journal of agricultural and food chemistry, 54(21), 8171-8176 (2006-10-13)
A study is made of the kinetics and mechanism of the reaction of radiolytically produced hydrated electron (e-(aq)) with some triazine derivatives [1,3,5-triazine (T), 2,4,6-trimethoxy-1,3,5-triazine (TMT), 2,4-dioxohexahydro-1,3,5-triazine (DHT), 6-chloro N-ethyl N-(1-methylethyl)-1,3,5-triazine 2,4-diamine (atrazine, AT), and cyanuric acid (CA)] in aqueous
Manuela Curcio et al.
Journal of agricultural and food chemistry, 58(22), 11883-11887 (2010-10-26)
A molecularly imprinted polymer able to recognize melamine in partially aqueous medium was synthesized using methacrylic acid as functional monomer and ethylene glycol dimethacrylate as cross-linking agent. The bound specificity and selectivity of the obtained material were verified by performing
Thermal rearrangement of cyanurates in the solid state.
Kaftory M and Handelsman-Benory E.
Mol. Cryst. Liq. Cryst., 240(1), 241-249 (1994)
Natalya Fridman et al.
Acta crystallographica. Section B, Structural science, 60(Pt 1), 97-102 (2004-01-22)
2,4,6-trimethoxy-1,3,5-triazine was found to exhibit three different polymorphs. The alpha-polymorph undergoes reversible phase transformation to the beta-polymorph at 340 K with an enthalpy of 3.9 kJ mol(-1). The heat of fusion of the beta-polymorph at 404 K is 18.1 kJ
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