Quality Level
assay
98%
mp
129-132 °C (lit.)
functional group
imide
SMILES string
CN1C(=O)c2ccccc2C1=O
InChI
1S/C9H7NO2/c1-10-8(11)6-4-2-3-5-7(6)9(10)12/h2-5H,1H3
InChI key
ZXLYYQUMYFHCLQ-UHFFFAOYSA-N
General description
目前业内已研究了用 2,3-二甲基-2-丁烯光还原 N-甲基邻苯二甲酰亚胺(NMP)。据报道,在静默和超声条件下,N-甲基邻苯二甲酰亚胺在离子液体和作为质子供体的苯酚中选择性电还原为 3-羟基-2-甲基-异吲哚啉-1-酮。研究了单电子转移(SET)诱导 NMP 与甲硅烷基烯醇醚的光化学反应。据报道,NMP 的硝化生成“专有地” 3-硝基衍生物。
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Nitration of N-alkylphthalimides.
Williams FJ and Donahue PE.
The Journal of Organic Chemistry, 43(8), 1608-1610 (1978)
Constanza Villagrán et al.
Ultrasonics sonochemistry, 12(6), 423-428 (2005-04-26)
The selective electroreduction N-methylphthalimide to 3-hydroxy-2-methyl-isoindolin-1-one has been performed in ionic liquids using phenol as a proton donor under silent and ultrasonic conditions. A significant increase in the rate of electroreduction is shown using ultrasonic activation and in addition high
Photoreduction of N-methylphthalimide with 2, 3-dimethyl-2-butene. Evidence for reaction through an electron transfer generated ion pair.
Mazzocchi PH and Klingler L.
Journal of the American Chemical Society, 106(24), 7567-7572 (1984)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 407992-5G | 04061831988413 |