408395
二甲基胺 N,N-二甲氨基甲酸酯
别名:
Dimcarb, 二甲胺二氧化碳络合物
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关于此项目
线性分子式:
(CH3)2NH · (CH3)2NCOOH
化学文摘社编号:
分子量:
134.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4531667
Form:
liquid
InChI
1S/C3H7NO2.C2H7N/c1-4(2)3(5)6;1-3-2/h1-2H3,(H,5,6);3H,1-2H3
SMILES string
CNC.CN(C)C(O)=O
InChI key
JIYXHCMRGZVYMA-UHFFFAOYSA-N
form
liquid
refractive index
n20/D 1.454 (lit.)
bp
60-61 °C (lit.)
density
1.05 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
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Application
主要用作溶剂的离子液体。
- 杯芳烃酮菁荧光团的合成
- 蒸馏法提取植物中的单宁
- 银 或铅在玻碳和汞膜电极上的电沉积
- Ag 和 Au 纳米结构的合成
- 用于合成单亚芳基环戊酮的可重复使用的反应介质
二甲基氨基甲酸二甲铵 (DIMCARB) 可用作二甲胺的等价物，其与羧酸反应生成 N,N -二甲基酰胺。它可以用作离子液体，用于合成在大环的宽边带有一个或两个酮花青素荧光团片段的杯形杯[4]芳烃。
General description
二甲基氨基甲酸铵 (DIMCARB) 是二甲胺的氨基甲酸酯盐。它被广泛用作溶剂和萃取剂。它是一种离子液体。DIMCARB是二甲胺与二氧化碳反应的产物 。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
55.4 °F - DIN 51758
flash_point_c
13 °C - DIN 51758
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Synthesis of calixarene-based ketocyanine fluorophores.
Matvieiev Y, et al.
Tetrahedron Letters, 52(30), 3922-3925 (2011)
Direct Catalytic Formation of Primary and Tertiary Amides from Non-Activated Carboxylic Acids, Employing Carbamates as Amine Source.
Tinnis F, et al.
Advanced Synthesis & Catalysis, 354(13), 2531-2536 (2012)
Dimethylammonium dimethylcarbamate (DIMCARB) as solvent and extractant.
Schroth W, et al.
Z. Chem., 73(1), 127-132 (1989)
Lam Phan et al.
The Journal of organic chemistry, 73(1), 127-132 (2007-12-11)
Known liquids that can reversibly switch their polarity at atmospheric pressure are all prepared as mixtures of two liquid components; we now report a series of switchable-polarity solvents that consist, in their low-polarity form, of only a single liquid component
K M Johansson et al.
Physical chemistry chemical physics : PCCP, 10(20), 2972-2978 (2008-05-14)
We describe a fluidity and conductivity study as a function of composition in N-methylpyrrolidine-acetic acid mixtures. The simple 1 : 1 acid-base mixture appears to form an ionic liquid, but its degree of ionicity is quite low and such liquids
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