氯三(三甲基甲硅烷基)硅烷

Name: 氯三(三甲基甲硅烷基)硅烷
Brand: ALDRICH

97%

别名:

1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane, 2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, Tris(trimethylsilyl)chlorosilane, Tris(trimethylsilyl)silyl chloride

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关于此项目

线性分子式:

[(CH₃)₃Si]₃SiCl

化学文摘社编号:

5565-32-2

分子量:

283.11

NACRES:

NA.22

PubChem Substance ID:

24865643

UNSPSC Code:

12352101

MDL number:

MFCD01321222

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产品名称

氯三(三甲基甲硅烷基)硅烷, 97%

InChI

1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3

SMILES string

C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C

InChI key

HCOROOJWVHFMRJ-UHFFFAOYSA-N

assay

97%

form

solid

mp

50-52 °C (lit.)

Quality Level

100

Application

Super Silyl Protecting Groups

Used for:

Insertion into a P-P bond
Diastereoselective aldol and cascade reactions
Preparation of hypersilyl substituted monophosphines and diphosphines

General description

Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.