409405
氯三(三甲基甲硅烷基)硅烷
97%
别名:
1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane, 2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, Tris(trimethylsilyl)chlorosilane, Tris(trimethylsilyl)silyl chloride
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关于此项目
线性分子式:
[(CH3)3Si]3SiCl
化学文摘社编号:
分子量:
283.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Assay:
97%
Form:
solid
Quality Segment
assay
97%
form
solid
reaction suitability
reactivity: alcohol reactive, reagent type: protection reagent
mp
50-52 °C (lit.)
functional group
silyl
SMILES string
C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3
InChI key
HCOROOJWVHFMRJ-UHFFFAOYSA-N
General description
Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.
Application
Super Silyl Protecting Groups
Used for:
Used for:
- Insertion into a P-P bond
- Diastereoselective aldol and cascade reactions
- Preparation of hypersilyl substituted monophosphines and diphosphines
警示词
Danger
靶器官
Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
怎么回事？
WGK 3
闪点 (F)
87.8 °F - closed cup
闪点 (°C)
31 °C - closed cup
PPE（个人防护设备）
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react. 3