410926
乙醇酸苯甲酯
97%
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线性分子式:
HOCH2CO2CH2C6H5
化学文摘社编号:
分子量:
166.17
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C9H10O3/c10-6-9(11)12-7-8-4-2-1-3-5-8/h1-5,10H,6-7H2
SMILES string
OCC(=O)OCc1ccccc1
InChI key
VPYJBEIOKFRWQZ-UHFFFAOYSA-N
assay
97%
form
liquid
refractive index
n20/D 1.527 (lit.)
bp
136 °C/14 mmHg (lit.)
density
1.171 g/mL at 25 °C (lit.)
functional group
ester, hydroxyl, phenyl
Quality Level
General description
乙醇酸苄酯是乙醇酸的一种苄基酯。
Application
乙醇酸苄酯可被用于合成[2-（2′-苄氧基-2′-氧乙基）-5-乙酰氨基-4,7,8,9-四-O-乙酰基-3,5-二脱氧-α-和-β-D-甘油-D-半乳糖-2-壬基吡喃糖苷]甲酯。它可用于制备单糖构建单元。它也可用于合成以下具有乙醇酸侧酯或以乳酸作为侧基的新型聚合磷腈：
- 聚[双（乙基乙二醇基）磷腈]
- 聚[双（乙基乳酸）磷腈]
- 聚[双（苄基乙二醇基）磷腈]
- 聚[双（苄基内氨基）磷腈]
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
Chien-Tai Ren et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 9(5), 1085-1095 (2003-02-22)
A facile synthesis of the sialic acid oligomers alpha-(2-->5)Neu5Gc (1) is presented. Monosaccharides 2-4 with suitable functionality were used as the building blocks. After selective removal of the paired carboxyl and amine protecting groups, the fully protected oligomers were assembled
Synthesis of poly (orgnaophosphazenes) with glycolic acid ester and lactic acid ester side groups: Prototypes for new bioerodible polymers.
Allcock HR, et al.
Macromolecules, 27(1), 1-4 (1994)
Chien-Tai Ren et al.
The Journal of organic chemistry, 67(4), 1376-1379 (2002-02-16)
The preparation of a disaccharide 2, Neu5Ac-alpha-(2-->5)Neu5Gc having a alpha-benzyl protecting group at the reducing end, by the coupling of the easily accessible building units 4 and 5 is described. Subsequent deprotection of the coupling adduct led to the isolation
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