411485
丙二酸二异丙酯
ReagentPlus®, 99%
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关于此项目
线性分子式:
(CH3)2CHO2CCH2CO2CH(CH3)2
化学文摘社编号:
分子量:
188.22
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
产品线
ReagentPlus®
方案
99%
表单
liquid
折射率
n20/D 1.412 (lit.)
沸点
93-95 °C/12 mmHg (lit.)
密度
0.991 g/mL at 25 °C (lit.)
官能团
ester
SMILES字符串
CC(C)OC(=O)CC(=O)OC(C)C
InChI
1S/C9H16O4/c1-6(2)12-8(10)5-9(11)13-7(3)4/h6-7H,5H2,1-4H3
InChI key
QRVSDVDFJFKYKA-UHFFFAOYSA-N
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应用
Diisopropyl malonates may be used in the synthesis of :
- 3-substituted coumarins
- 2-carboisopropoxy-3-hydroxyquinoxaline-di-N-oxide
- 2-carboisopropoxy-3-hydroxy-6-methoxylquinoxaline-di-N-oxide
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
192.2 °F - closed cup
闪点(°C)
89 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Yingjun Xu et al.
Molecules (Basel, Switzerland), 16(8), 6894-6901 (2011-08-16)
A series of quinoxaline 1,4-di-N-oxide analogues were prepared from benzofurazan N-oxide derivatives and β-diketone ester compounds by the improved Beirut reaction. The structures of the target products were characterized by NMR, MS, IR and elemental analysis measurements, and that of
A Catalytic Enantioselective Michael Addition of a Simple Malonate to Prochiral a, ?-Unsaturated Ketoses and Aldehydes.
Yamaguchi M, et al.
Angewandte Chemie (International Edition in English), 32(8), 1176-1178 (1993)
H Jinno et al.
Archives of toxicology, 71(9), 550-555 (1997-01-01)
The fungicide isoprothiolane (diisopropyl 1,3-dithiolane-2-ylidenemalonate) decomposes to the diisopropyl esters of malonic acid (DM), chloromalonic acid (DCM) and dichloromalonic acid (DDCM) upon aqueous chlorination. In this study, the cytotoxicity of these compounds was examined using rat hepatocytes cultured on Matrigel.
Use of isopropyl alcohol as a solvent in Ti (O-i-Pr) 4-catalyzed Knoevenagel reactions.
Yamashita K, et al.
Tetrahedron, 61(33), 7981-7985 (2005)
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