Merck
CN

412260

Sigma-Aldrich

苯氧肟酸

99%

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别名:
苯甲羟肟酸
线性分子式:
C6H5CONHOH
CAS号:
分子量:
137.14
Beilstein:
1907585
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99%

mp

126-130 °C (lit.)

溶解性

1 M NaOH: soluble 50 mg/mL, clear, colorless

储存温度

2-8°C

SMILES string

ONC(=O)c1ccccc1

InChI

1S/C7H7NO2/c9-7(8-10)6-4-2-1-3-5-6/h1-5,10H,(H,8,9)

InChI key

VDEUYMSGMPQMIK-UHFFFAOYSA-N

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此商品
S607185329M0375
Benzhydroxamic acid 99%

Sigma-Aldrich

412260

苯氧肟酸

Salicylhydroxamic acid 99%

Sigma-Aldrich

S607

水杨羟肟酸

3-Nitrobenzoic acid ReagentPlus®, 99%

Sigma-Aldrich

185329

3-硝基苯甲酸

Maleic acid ReagentPlus®, ≥99% (HPLC)

Sigma-Aldrich

M0375

马来酸

mp

126-130 °C (lit.)

mp

177 °C (dec.) (lit.)

mp

139-141 °C (lit.)

mp

130-135 °C (lit.)

solubility

1 M NaOH: soluble 50 mg/mL, clear, colorless

solubility

-

solubility

water: soluble 3 g/L at 25 °C

solubility

-

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

一般描述

苯异羟肟酸(BHA)与BiPh3或Bi(O(t)Bu)3反应,得到具有抗幽门螺杆菌活性的新型单阴离子和二阴离子异羟肟酸复合物。 已研究了重组辣根过氧化物酶-BHA复合物的三维结构。

应用

苯异羟肟酸可用于Pd催化的苯并异恶唑酮合成。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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A Henriksen et al.
Biochemistry, 37(22), 8054-8060 (1998-06-12)
The three-dimensional structure of recombinant horseradish peroxidase in complex with BHA (benzhydroxamic acid) is the first structure of a peroxidase-substrate complex demonstrating the existence of an aromatic binding pocket. The crystal structure of the peroxidase-substrate complex has been determined to
Florian Thaler et al.
Journal of medicinal chemistry, 53(2), 822-839 (2009-12-19)
The histone deacetylases (HDACs) are able to regulate gene expression, and histone deacetylase inhibitors (HDACi) emerged as a new class of agents in the treatment of cancer as well as other human disorders such as neurodegenerative diseases. In the present
Swetlana Gez et al.
Inorganic chemistry, 44(8), 2934-2943 (2005-04-12)
A new family of relatively stable Cr(V) complexes, [Cr(V)O(L)(2)](-) (LH(2) = RC(O)NHOH, R = Me, Ph, 2-HO-Ph, or HONHC(O)(CH(2))(6)), has been obtained by the reactions of hydroxamic acids with Cr(VI) in polar aprotic solvents. Similar reactions in aqueous solutions led
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Journal of the American Chemical Society, 132(20), 6908-6909 (2010-05-04)
An external-oxidant-free process to access the isoquinolone motif via cross-coupling/cyclization of benzhydroxamic acid with alkynes is described. The reaction features a regioselective cleavage of a C-H bond on the benzhydroxamic acid coupling partner as well as a regioselective alkyne insertion.
Henrik R Hallingbäck et al.
Biochemistry, 45(9), 2940-2950 (2006-03-01)
The oxidation of melatonin by the mammalian myeloperoxidase (MPO) provides protection against the damaging effects of reactive oxygen species. Indole derivatives, such as melatonin and serotonin, are also substrates of the plant horseradish peroxidase (HRP), but this enzyme exhibits remarkable

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