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Merck
CN

412287

Sigma-Aldrich

均苯四甲酸酐

97%

别名:

1,2,4,5-苯四甲羧酸二酐, PMDA

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关于此项目

经验公式(希尔记法):
C10H2O6
CAS Number:
分子量:
218.12
Beilstein:
213583
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23
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质量水平

方案

97%

表单

powder

沸点

397-400 °C (lit.)

mp

283-286 °C (lit.)

SMILES字符串

O=C1OC(=O)c2cc3C(=O)OC(=O)c3cc12

InChI

1S/C10H2O6/c11-7-3-1-4-6(10(14)16-8(4)12)2-5(3)9(13)15-7/h1-2H

InChI key

ANSXAPJVJOKRDJ-UHFFFAOYSA-N

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一般描述

均苯四甲酸二酐是二酐类单体,常用于制备聚酰亚胺聚合物,这类聚合物因其优异的热稳定性、高机械强度和固有的阻燃性而用于航空航天、电子和汽车工业领域。它还用于合成聚酯和聚醚等热塑性聚合物,以及增塑剂和环氧树脂。另外,PMDA还可作为环氧树脂的固化剂。环氧树脂广泛用于粘合剂、涂料、复合材料和电绝缘材料。

均苯四甲酸二酐(PMDA)是一种酸性酸酐,可作为修复剂和扩链剂用于聚对苯二甲酸乙二醇酯(PET)扩链反应。它主要用于生产热塑性塑料和其他涂料应用。

应用

PMDA可用作:
  • 单体,合成具有优良热机械性能和化学特性的芳香族聚酰亚胺。这些聚合物可应用于汽车和电子行业。
  • 封端剂,研发硅氧烷基杂化材料,在有机电子领域具有潜在应用。
  • 单体,制备和改性薄膜复合膜,用于水净化、气体分离和生物医学设备。
  • 单体,合成均苯四甲酸二酰亚胺共聚物,作为锂离子电池和钠离子电池的稳定性正极活性材料。

象形图

Health hazardCorrosion

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Resp. Sens. 1 - Skin Sens. 1

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

716.0 °F - closed cup

闪点(°C)

380 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Jun-Xia Yu et al.
Environmental science and pollution research international, 20(1), 543-551 (2012-04-25)
The purpose of this research is to use a simple method to prepare magnetic modified biomass with good adsorption performances for cationic ions. The magnetic modified biomass was prepared by two steps: (1) preparation of pyromellitic dianhydride (PMDA) modified biomass
Anastasia Anceschi et al.
Nanomaterials (Basel, Switzerland), 10(3) (2020-03-12)
Cyclodextrin (CD)-based polymers are known to efficiently form molecular inclusion complexes with various organic and inorganic guest compounds. In addition, they also have a great potential as metal complexes because deprotonated hydroxyls can strongly bind metal ions under alkaline conditions.
Shadpour Mallakpour et al.
Amino acids, 43(4), 1605-1613 (2012-02-14)
In the present work, several novel optically active nanostructure poly(amide-imide)s (PAI)s were synthesized via step-growth polymerization reaction of chiral diacids based on pyromellitic dianhydride-derived dicarboxylic acids containing different natural amino acids such as L-alanine, S-valine, L-leucine, L-isoleucine, L-methionine, and L-phenylalanine
Yuta Nabae et al.
Scientific reports, 6, 23276-23276 (2016-03-19)
The development of a non-precious metal (NPM) fuel cell catalyst is extremely important to achieve globalization of polymer electrolyte fuel cells due to the cost and scarcity of platinum. Here, we report on a NPM cathode catalyst prepared by the
Claudio Cecone et al.
Molecules (Basel, Switzerland), 23(7) (2018-07-13)
Electrospun beta-cyclodextrin (βCD)-based polymers can combine a high surface-to-volume ratio and a high loading/controlled-release-system potential. In this work, pyromellitic dianhydride (PMDA)/βCD-based nanosponge microfibers were used to study the capability to host a common insect repellent (N,N-diethyl-3-toluamide (DEET)) and to monitor

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