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Merck
CN

414492

2-三丁基甲锡烷基噻吩

97%

别名:

2-(三丁基锡)噻吩, 2-噻吩基三丁基锡, 三丁基(噻吩-2-基)锡烷, 三丁基-2-噻吩基锡烷, 三丁基噻吩-2-基锡烷

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关于此项目

经验公式(希尔记法):
C16H30SSn
化学文摘社编号:
分子量:
373.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Assay:
97%
Form:
liquid
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产品名称

2-三丁基甲锡烷基噻吩, 97%

InChI

1S/C4H3S.3C4H9.Sn/c1-2-4-5-3-1;3*1-3-4-2;/h1-3H;3*1,3-4H2,2H3;

SMILES string

CCCC[Sn](CCCC)(CCCC)c1cccs1

InChI key

UKTDFYOZPFNQOQ-UHFFFAOYSA-N

assay

97%

form

liquid

refractive index

n20/D 1.518 (lit.)

bp

155 °C/0.1 mmHg (lit.)

density

1.175 g/mL at 25 °C (lit.)

Quality Level

Application

以 2-三丁基锡基噻吩为原料,合成了电致变色聚合物用二苯基喹喔啉单体。它也可用作斯蒂尔偶联反应的反应物。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

221.0 °F - closed cup

flash_point_c

105 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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John A Roque et al.
Inorganic chemistry, 59(22), 16341-16360 (2020-11-01)
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Synthesis, emission and spectro-electrochemical studies of bithienylnaphthalene systems.
Sankaran B, et al.
Synthetic Metals, 123(3), 425-433 (2001)
Two-dimensional structural motif in thienoacene semiconductors: Synthesis, structure, and properties of tetrathienoanthracene isomers.
Brusso JL, et al.
Chemistry of Materials, 20(7), 2484-2494 (2008)
Matteo Atzori et al.
Organic & biomolecular chemistry, 12(43), 8752-8763 (2014-09-30)
2,5-Bis(thiophene) and 2,5-bis(ethylenedioxy-thiophene) (EDOT) derivatives of 3,6-diethoxy-1,4-benzoquinone (para isomers) were prepared by Stille coupling between the 2,5-dibromo-3,6-diethoxy-1,4-benzoquinone precursors and (n-Bu)3Sn-R (R = 2-thiophenyl or 3,4-ethylenedioxy-2-thiophenyl) reagents. In a parallel series of experiments 2,6-bis(thiophene) and 2,6-EDOT-3,5-diethoxy-1,4-benzoquinone (meta isomers) were synthesized by
Microwave synthesis and fluorous purification of 4-(tetrathienyl) butyric acid for self-assembled monolayer semiconductor applications.
McCairn MC, et al.
Tetrahedron Letters, 49(8), 1328-1330 (2008)

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