产品名称
7-氧杂二环[4.1.0]庚-2-酮, 98%
InChI key
QKOHEJBTNOEACF-UHFFFAOYSA-N
InChI
1S/C6H8O2/c7-4-2-1-3-5-6(4)8-5/h5-6H,1-3H2
SMILES string
O=C1CCCC2OC12
assay
98%
form
liquid
refractive index
n20/D 1.474 (lit.)
bp
76-78 °C/15 mmHg (lit.)
density
1.13 g/mL at 25 °C (lit.)
functional group
ether
ketone
Quality Level
Application
7-Oxabicyclo[4.1.0]heptan-2-one was employed as substrate to investigate the substrate specificity of purified recombinant NADPH-dependent 3-quinuclidinone reductases from Microbacterium luteolum JCM 9174 for the reductive reaction of ketones.
General description
7-Oxabicyclo[4.1.0]heptan-2-one is one of the products formed during oxidation of cyclohexene by dendritic complexes. It has been reported as anticapsin analog.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
204.8 °F - closed cup
flash_point_c
96.00 °C - closed cup
ppe
Eyeshields, Gloves
Oxidation of cyclohexene by dendritic PAMAMSA-Mn (II) complexes.
Yang Z-W, et al.
J. Mol. Catal. A: Chem., 213(2), 169-176 (2004)
Kentaro Isotani et al.
Applied and environmental microbiology, 79(4), 1378-1384 (2012-12-25)
We used the resting-cell reaction to screen approximately 200 microorganisms for biocatalysts which reduce 3-quinuclidinone to optically pure (R)-(-)-3-quinuclidinol. Microbacterium luteolum JCM 9174 was selected as the most suitable organism. The genes encoding the protein products that reduced 3-quinuclidinone were
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