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Merck
CN

41541

1,8-双(四甲基胍基)萘

≥98.0%

别名:

N′′,N′′′′′-1,8-萘二基双(N,N,N′,N′-四甲基-胍), TMGN

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关于此项目

线性分子式:
C10H6[N=C[N(CH3)2]2]2
化学文摘社编号:
分子量:
354.49
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥98.0%
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assay

≥98.0%

impurities

≤0.5% water

mp

124-128 °C

solubility

toluene: 20 mg/mL, clear

functional group

amine

SMILES string

CN(C)\C(=N\c1cccc2cccc(\N=C(\N(C)C)N(C)C)c12)N(C)C

InChI

1S/C20H30N6/c1-23(2)19(24(3)4)21-16-13-9-11-15-12-10-14-17(18(15)16)22-20(25(5)6)26(7)8/h9-14H,1-8H3

InChI key

PSHHYQWGIGYWHP-UHFFFAOYSA-N

Analysis Note

可能含深色颗粒


ppe

Eyeshields, Gloves, type N95 (US)

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

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Volker Raab et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 8(7), 1682-1693 (2002-04-05)
1,8-Bis(tetramethylguanidino)naphthalene (TMGN, 1) is a new, readily accessible, and stable "proton sponge" with an experimental pK(BH(+)) value of 25.1 in MeCN, which is nearly seven orders of magnitude higher in basicity than the classical proton sponge 1,8-bis(dimethylamino)-naphthalene (DMAN). Because of
Strong Organic Bases as Building Blocks of Mesoporous Hybrid Catalysts for C-C Forming Bond Reactions.
Gianotti E, et al.
European Journal of Inorganic Chemistry, 32, 5175-5185 (2012)
Dong Cao et al.
Talanta, 85(1), 345-352 (2011-06-08)
Determination of perfluorinated compounds (PFCs) is very important because of their potential hazards to the environment and human health. In present work, 1,8-bis (tetramethylguanidino)-naphthalene (TMGN), a superbasic proton sponge, was firstly employed as the matrix for quantitative detection of acidic



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货号GTIN
41541-5G-F04061832969138
41541-1G-F04061826652527