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Merck
CN

415952

(2,4,6-三甲基苯甲酰基)二苯基氧化膦

97%

别名:

(2,4,6-三甲基苯甲酰基)二苯基氧化膦, (二苯膦氧基)(均三甲苯基)甲酮, 2,4,6-三甲基苯甲酰基苯基膦酸酯

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关于此项目

线性分子式:
(CH3)3C6H2COP(O)(C6H5)2
化学文摘社编号:
分子量:
348.37
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
EC Number:
278-355-8
MDL number:
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产品名称

(2,4,6-三甲基苯甲酰基)二苯基氧化膦, 97%

InChI key

VFHVQBAGLAREND-UHFFFAOYSA-N

InChI

1S/C22H21O2P/c1-16-14-17(2)21(18(3)15-16)22(23)25(24,19-10-6-4-7-11-19)20-12-8-5-9-13-20/h4-15H,1-3H3

SMILES string

Cc1cc(C)c(c(C)c1)C(=O)P(=O)(c2ccccc2)c3ccccc3

assay

97%

form

powder

mp

88-92 °C (lit.)

Quality Level

Application

TPO可用于PMMA复合材料的光交联反应,进而用作有机薄膜晶体管(OTFT)中的栅极绝缘体。这一成分还可用于形成紫外线固化聚氨酯丙烯酸酯涂层。此外,它还可用于光诱导反应以形成有机膦化合物,进而可能用作金属催化剂的配体和试剂。

General description

(2,4,6-三甲基苯甲酰基)二苯基氧化膦(TPO)是一种基于单酰基氧化膦的光引发剂,可掺入各种聚合物基质,以实现有效固化树脂并确保其颜色稳定性。

Preparation Note

光敏性

signalword

Warning

Hazard Classifications

Aquatic Chronic 2 - Repr. 2 - Skin Sens. 1

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

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Amirali Nojoomi et al.
Nature communications, 12(1), 603-603 (2021-01-29)
Two-dimensional (2D) growth-induced 3D shaping enables shape-morphing materials for diverse applications. However, quantitative design of 2D growth for arbitrary 3D shapes remains challenging. Here we show a 2D material programming approach for 3D shaping, which prints hydrogel sheets encoded with
Coating performance and characteristics for UV-curable aliphatic urethane acrylate coatings containing norrish type I photoinitiators
Lee B, et al.
Journal of Coatings Technology and Research, 3(3), 221-229 (2006)
Photoinduced reductive perfluoroalkylation of phosphine oxides: synthesis of P-perfluoroalkylated phosphines using TMDPO and perfluoroalkyl iodides
Sato Y, et al.
Chemical Communications (Cambridge, England), 51(52), 10385-10388 (2015)
PMMA-based patternable gate insulators for organic thin-film transistors
Kim TG, et al.
Synthetic Metals, 159(7-8), 749-753 (2009)
Andrew V Healy et al.
Pharmaceutics, 11(12) (2019-12-11)
The introduction of three-dimensional printing (3DP) has created exciting possibilities for the fabrication of dosage forms, paving the way for personalized medicine. In this study, oral dosage forms of two drug concentrations, namely 2.50% and 5.00%, were fabricated via stereolithography

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