416126
三羟甲基丙烷二烯丙基醚
90%
别名:
2,2-双(烯丙氧基甲基)-1-丁醇
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关于此项目
线性分子式:
C2H5C(CH2OCH2CH=CH2)2CH2OH
化学文摘社编号:
分子量:
214.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
EC Number:
211-661-1
MDL number:
InChI key
BDKDHWOPFRTWPP-UHFFFAOYSA-N
InChI
1S/C12H22O3/c1-4-7-14-10-12(6-3,9-13)11-15-8-5-2/h4-5,13H,1-2,6-11H2,3H3
SMILES string
CCC(CO)(COCC=C)COCC=C
assay
90%
form
liquid
refractive index
n20/D 1.458 (lit.)
bp
135 °C/13 mmHg (lit.)
density
0.955 g/mL at 25 °C (lit.)
Quality Level
General description
三羟甲基丙烷二烯丙基醚（TMPAE）是一种不饱和烯丙基醚，可以以三羟甲基丙烷、氢氧化钠和烯丙基氯为原料通过Williamson酯化反应合成。
Application
TMPAE 可用于合成异佛尔酮二异氰酸酯（IPDI）类并四苯单体，其可进一步用于形成聚合物分散液晶。它还可用于合成有望用于涂料的烯丙基醚类树状聚合物。
Other Notes
残留有单醚和三醚
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
244.4 °F - closed cup
flash_point_c
118 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Synthesis and thiol-ene photopolymerization of allyl-ether functionalized dendrimers
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Journal of Polymer Science Part A: Polymer Chemistry, 46(4), 1339-1348 (2008)
Thermal and Mechanical Properties of Cross-Linked Photopolymers Based on Multifunctional Thiol- Urethane Ene Monomers
Senyurt AF, et al.
Macromolecules, 40(9), 3174-3182 (2007)
Visible light induced polymerization of maleimide-vinyl and maleimide-allyl ether based systems
Burget D, et al.
Polymer, 44(25), 7671-7678 (2003)
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