416428
2,2′-亚甲基双[(4S)-4-苯基-2-噁唑啉]
97%
别名:
(S,S)-2,2′-亚甲基双(4-苯基-2-噁唑啉)
选择尺寸
关于此项目
InChI
1S/C19H18N2O2/c1-3-7-14(8-4-1)16-12-22-18(20-16)11-19-21-17(13-23-19)15-9-5-2-6-10-15/h1-10,16-17H,11-13H2/t16-,17-/m1/s1
SMILES string
C1OC(CC2=N[C@H](CO2)c3ccccc3)=N[C@H]1c4ccccc4
InChI key
IUFHJPXOLHSJTC-IAGOWNOFSA-N
assay
97%
form
viscous liquid
optical activity
[α]20/D ~−90°, c = 1 in ethanol
refractive index
n20/D 1.586 (lit.)
bp
131-134 °C/0.01 mmHg (lit.)
density
1.28 g/mL at 25 °C (lit.)
functional group
ether, phenyl
Quality Level
Application
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
商品
BOX ligand complex enhances catalytic enantioselective aziridination of styrene, with phenyl substituents proving superior over t-Bu groups.
使用络合Cu(I)OTf的BOX配体进行不对称催化苯乙烯合成氮杂环丙烷的反应，BOX配体带苯基取代基的优于具有位阻需求的叔丁(t-Bu)基团。
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