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Merck
CN

416665

叔丁基过氧化氢 溶液

5.0-6.0 M in decane

别名:

1,1-二甲基乙基-过氧化氢, 2-过氧化氢-2-甲基丙烷, TBHP

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关于此项目

线性分子式:
(CH3)3COOH
化学文摘社编号:
分子量:
90.12
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1098280
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form

liquid

Quality Level

reaction suitability

reagent type: oxidant

concentration

5.0-6.0 M in decane, 55.4-65.1% (Thiosulphate, titration)

impurities

<4% water

refractive index

n20/D 1.402

density

0.808 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

General description

叔丁基氢过氧化物是一种有机过氧化物,可用于氧化过程。

Application

叔丁基氢过氧化物可用于:
锇催化烯烃在碱性条件下的邻位羟基化
使用联萘酚作为手性助剂,将硫化物催化不对称氧化成亚砜
二苯并噻吩的氧化


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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

5.2 - Organic peroxides and self-reacting hazardous materials

flash_point_f

109.4 °F - closed cup

flash_point_c

43 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Wang D, et al.
Applied Catalysis A: General, 91-99 (2003)
Osmium catalyzed vicinal hydroxylation of olefins by tert-butyl hydroperoxide under alkaline conditions.
Sharpless KB and Akashi K
Journal of the American Chemical Society, 98(7), 1986-1987 (1976)
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The Journal of Organic Chemistry, 58(17), 4529-4533 (1993)



全球贸易项目编号

货号GTIN
416665-25ML04061832089782
416665-100ML04061832089775
416665-1L04065274119076