416754
氯仿-d
≥99.8 atom % D, contains 0.5 wt. % silver foil as stabilizer
别名:
氘代氯仿
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关于此项目
线性分子式:
CDCl3
化学文摘社编号:
分子量:
120.38
UNSPSC Code:
12142201
NACRES:
NA.21
PubChem Substance ID:
EC Number:
212-742-4
Beilstein/REAXYS Number:
1697633
MDL number:
Isotopic purity:
≥99.8 atom % D
Assay:
≥99.00%
Mass shift:
M+1
Form:
liquid
InChI key
HEDRZPFGACZZDS-MICDWDOJSA-N
InChI
1S/CHCl3/c2-1(3)4/h1H/i1D
SMILES string
[2H]C(Cl)(Cl)Cl
isotopic purity
≥99.8 atom % D
assay
≥99.00%
form
liquid
contains
0.5 wt. % silver foil as stabilizer
Quality Level
impurities
≤0.0100% water
water
refractive index
n20/D 1.444 (lit.)
bp
60.9 °C (lit.)
mp
−64 °C (lit.)
density
1.500 g/mL at 25 °C (lit.)
mass shift
M+1
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General description
氯仿-d（氘代氯仿，CDCl3）是一种氘代NMR溶剂，可用于基于NMR的研究和分析中。它可以通过使用三氯苯乙酮与十二烷氧化钠反应来合成。 脉冲数对其多光子分解（MPD）的影响已有研究。 CDCl3在不同的溶剂中C-D拉伸和弯曲运动的红外光谱研究已有报道。 氯仿-d对水与活性炭相互作用的影响已有分析。 研究人员通过拉曼光谱研究了氘代氯仿的分子重新取向对压力和温度的依赖性。
Application
氯仿-d可用于合成二氯氟甲烷-d。
Other Notes
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3
target_organs
Central nervous system, Liver,Kidney
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
does not flash
flash_point_c
does not flash
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Gianni Colotti et al.
Amino acids, 52(2), 247-259 (2019-05-01)
Leishmania protozoans are the causative agent of leishmaniasis, a neglected tropical disease consisting of three major clinical forms: visceral leishmaniasis (VL), cutaneous leishmaniasis, and mucocutaneous leishmaniasis. VL is caused by Leishmania donovani in East Africa and the Indian subcontinent and
The effect of collisions in the multiphoton decomposition of chloroform-d.
McRae GA, et al.
J. Chem. Phys. , 92(10), 5997-6003 (1990)
Isotope Effect on Dissociation Probabilities in the Mass Spectra of Chloroform and Chloroform-d.
Dibeler VH and Bernstein RB.
J. Chem. Phys. , 19(4), 404-406 (1951)
Raman study of molecular reorientation in liquid chloroform and chloroform-d under high pressure.
Schroeder J, et al.
J. Chem. Phys. , 69(12), 5479-5488 (1978)
Influence of organics on the structure of water adsorbed on activated carbons.
Turov VV, et al.
Journal of Colloid and Interface Science, 253(1), 23-34 (2002)
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