418102
丁醛
purified by redistillation, ≥99.5%
别名:
正丁醛
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关于此项目
线性分子式:
CH3CH2CH2CHO
化学文摘社编号:
分子量:
72.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-646-6
Beilstein/REAXYS Number:
506061
MDL number:
Assay:
≥99.5%
Form:
liquid
vapor density
2.5 (vs air)
Quality Level
vapor pressure
90 mmHg ( 20 °C)
assay
≥99.5%
form
liquid
autoignition temp.
390 °F
purified by
redistillation
expl. lim.
12.5 %
refractive index
n20/D 1.380 (lit.)
bp
75 °C (lit.)
mp
−96 °C (lit.)
density
0.8 g/mL at 25 °C (lit.)
functional group
aldehyde
organoleptic
pungent
SMILES string
[H]C(=O)CCC
InChI
1S/C4H8O/c1-2-3-4-5/h4H,2-3H2,1H3
InChI key
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N
General description
丁醛，又称正丁醛，是一种脂肪醛，常用作各种有机反应中的多功能合成砌块，例如可合成各种C4–C8醇、酯、胺和羧酸。
Application
丁醛可用作以下反应物：
- 各种硝基芳烃衍生物的还原胺化反应合成单-N-烷基苯胺衍生物。
- 离子液体催化 Knoevenagel 与活性亚甲基化合物缩合，合成取代的亲电烯烃。
- NiCl2通过与胺和三甲基甲硅烷基氰化物反应催化合成 α-氨基腈。
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signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2
存储类别
3 - Flammable liquids
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
flash_point_f
12.2 °F - closed cup
flash_point_c
-11 °C - closed cup
法规信息
危险化学品
此项目有
Heterogeneous photocatalytic oxidation of gas-phase organics for air purification: acetone, 1-butanol, butyraldehyde, formaldehyde, and m-xylene oxidation.
Peral J and Ollis DF.
J. Catal., 1136(2), 554-565 (1992)
The condensation of butyraldehyde and aniline.
Kharasch MS, et al.
Journal of the American Chemical Society, 62(3), 494-497 (1940)
Phosphazene base promoted anionic polymerization of n-butyraldehyde
Inge W, et al.
European Polymer Journal, 93, 97-102 (2017)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 418102-800ML | 04061832091013 |
| 418102-100ML | 04061832090986 |