4-(三甲基硅基)-3-丁炔-2-酮

Name: 4-(三甲基硅基)-3-丁炔-2-酮
Brand: ALDRICH

97%

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About This Item

线性分子式:

(CH₃)₃SiC≡CCOCH₃

CAS Number:

5930-98-3

分子量:

140.26

MDL编号:

MFCD00190212

UNSPSC代码:

12352100

PubChem化学物质编号:

24866234

NACRES:

NA.22

质量水平

100

方案

97%

表单

liquid

折射率

n20/D 1.442 (lit.)

沸点

156 °C (lit.)

密度

0.854 g/mL at 25 °C (lit.)

官能团

ketone

SMILES字符串

CC(=O)C#C[Si](C)(C)C

InChI

1S/C7H12OSi/c1-7(8)5-6-9(2,3)4/h1-4H3

InChI key

NQEZDDPEJMKMOS-UHFFFAOYSA-N

一般描述

4-(Trimethylsilyl)-3-butyn-2-one is a ketone. Its asymmetric bioreduction to enantiopure {(S)-TMSBOL in various hydrophilic ionic liquid (ILs) solvent systems has been reported.

应用

4-(Trimethylsilyl)-3-butyn-2-one (TMSB) has been used to investigate its asymmetric bioreduction to (S)-4-(trimethylsilyl)-3-butyn-2-ol {(S)-TMSBOL} by employing biocompatible water-immiscible ionic liquids (ILs). TMSB may be used for the synthesis of entecavir (BMS-200475).