419206
苄基(三苯基膦)乙酸酯
97%
别名:
(Benzyloxycarbonylmethylene)triphenylphosphorane, 2-(Triphenylphosphoranylidene)acetic acid phenylmethyl ester
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关于此项目
线性分子式:
(C6H5)3P=CHCO2CH2C6H5
化学文摘社编号:
分子量:
410.44
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
MDL number:
Assay:
97%
InChI
1S/C27H23O2P/c28-27(29-21-23-13-5-1-6-14-23)22-30(24-15-7-2-8-16-24,25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20,22H,21H2
SMILES string
O=C(OCc1ccccc1)C=P(c2ccccc2)(c3ccccc3)c4ccccc4
InChI key
INKMLGJBBDRIQR-UHFFFAOYSA-N
assay
97%
reaction suitability
reaction type: C-C Bond Formation
mp
120-122 °C (lit.)
functional group
ester, phenyl, phosphine
Quality Level
Application
Reactant for:
- Tributylphosphine-mediated vinylogous Wittig reactions
- Synthesis of 1,2-dioxanes for antitrypanosomal activity
- Organocatalytic Michael-type reactions / Wittig reactions of phosphorus ylides and unsaturated ketones
- Stereoselective phosphine-catalyzed cycloaddition to form spirocyclopenteneoxindoles
- Enantioselective synthesis of pantothenic acid
- Preparation of phosphorus ylides from phosphoranes and acetic anhydride
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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