419214
2,6-二溴庚二酸二甲酯
97%
别名:
2,6-二溴庚二酸二甲基酯
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关于此项目
线性分子式:
CH2[CH2CH(Br)CO2CH3]2
化学文摘社编号:
分子量:
346.01
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
liquid
InChI
1S/C9H14Br2O4/c1-14-8(12)6(10)4-3-5-7(11)9(13)15-2/h6-7H,3-5H2,1-2H3
SMILES string
COC(=O)C(Br)CCCC(Br)C(=O)OC
InChI key
AWWJYEJSCIDADZ-UHFFFAOYSA-N
assay
97%
form
liquid
greener alternative product score
old score: 2
new score: 1
Find out more about DOZN™ Scoring
greener alternative product characteristics
Waste Prevention
Safer Solvents and Auxiliaries
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
refractive index
n20/D 1.501 (lit.)
bp
130-140 °C/0.01 mmHg (lit.)
density
1.59 g/mL at 25 °C (lit.)
functional group
bromo, ester
greener alternative category
Quality Level
General description
2,6-二溴庚烷二甲酸二甲酯在各种聚合反应中作为双功能引发剂发挥作用。它的电化学环化反应可以得到三至六元的 1,2-环烷酸二甲酯。
我们竭诚为您带来满足绿色替代产品四大类别要求的替代产品。本品属于重新设计产品类别，在“防止废弃物防”、“更安全的溶剂和助剂”和“节能设计”绿色化学原则方面取得了重大进步。 点击此处查看其DOZN记分卡。
Application
2,6-二溴庚二酸二甲酯可用于以下研究：
- 双官能团聚（ n -丙烯酸丁酯）(pBA) 大引发剂的制备。
- 用原子转移自由基聚合 (ATRP) 合成了端二溴聚苯乙烯。
- 合成了一种用于自由基聚合反应的可逆加成-断裂链转移 (RAFT) 试剂。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Multiblock Copolymers of Styrene and Butyl Acrylate via Polytrithiocarbonate-Mediated RAFT Polymerization.
Ebeling B and Vana P.
Polymers (Basel, Switzerland), 3(2), 719-739 (2011)
Reversible redox cleavage/coupling of polystyrene with disulfide or thiol groups prepared by atom transfer radical polymerization.
Tsarevsky NV and Matyjaszewski K.
Macromolecules, 35(24), 9009-9014 (2002)
ABA triblock copolymers containing polyhedral oligomeric silsesquioxane pendant groups: synthesis and unique properties.
Pyun J, et al.
Polymer, 44(9), 2739-2750 (2003)
Synthesis of Dimethyl 1, 2-Cycloalkanedicarboxylates by Electrochemical Cyclization of Dimethyl a, a'-Dibromoalkanedioates Using a Copper Anode.
Tokuda M, et al.
Bulletin of the Chemical Society of Japan, 64(8), 2590-2592 (1991)
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