420697
N-(甲氧基甲基)-N-(三甲基硅烷基甲基)苄胺
96%
别名:
N-(Methoxymethyl)-N-(trimethylsilylmethyl)-N-benzylamine, N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine, Benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine
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关于此项目
线性分子式:
C6H5CH2N(CH2OCH3)CH2Si(CH3)3
化学文摘社编号:
分子量:
237.41
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Assay:
96%
Form:
liquid
Quality Level
assay
96%
form
liquid
refractive index
n20/D 1.492 (lit.)
bp
76 °C/0.3 mmHg (lit.)
density
0.928 g/mL at 25 °C (lit.)
functional group
amine, ether, phenyl
SMILES string
COCN(Cc1ccccc1)C[Si](C)(C)C
InChI
1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3
InChI key
RPZAAFUKDPKTKP-UHFFFAOYSA-N
Application
形成偶氮甲碱叶立德，易于进行 [3+2] 环加成反应，生成能够提供高产率 N-苄基取代吡咯烷的 α,β-不饱和酯。
用于在实际大量合成手性吡咯烷中进行不对称 1,3-偶极环加成反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
150.8 °F - closed cup
flash_point_c
66 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Kotian, Pravin L.; et al.
Organic Process Research & Development, 9(2), 193-197 (2005)
Synthesis, 2646-2646 (2006)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 420697-100G | 04061833547519 |
| 420697-5G | 04061837790386 |
| 420697-25G | 04061833509685 |