(1S)-(+)-酮基蒎酸

Name: (1<I>S</I>)-(+)-酮基蒎酸
Brand: ALDRICH

99%

别名:

(1S)-7,7-二甲基-2-氧代二环[2.2.1]庚烷-1-甲酸

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经验公式（希尔记法）:

C₁₀H₁₄O₃

CAS Number:

分子量:

182.22

Beilstein:

4180005

MDL编号:

UNSPSC代码:

12352115

PubChem化学物质编号:

NACRES:

NA.22

99%

[α]23/D +58°, c = 1 in chloroform

237-239 °C (lit.)

carboxylic acid
ketone

CC1(C)C2CCC1(C(O)=O)C(=O)C2

1S/C10H14O3/c1-9(2)6-3-4-10(9,8(12)13)7(11)5-6/h6H,3-5H2,1-2H3,(H,12,13)/t6-,10+/m1/s1

WDODWBQJVMBHCO-LDWIPMOCSA-N

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(1S)-(+)-Ketopinic acid is a chiral ketone.

用于制备新型手性噁唑烷酮辅助剂和酮基蒎酸衍生聚合物，该聚合物可用于胺的去外消旋化。合成纯手性 2,10-莰烷二醇的原料。用于生成手性席夫碱前体，以制备二乙基 (S)-α-氨基-α-烷基膦酸酯。

(1S)-(+)-Ketopinic acid may be used to prepare:

Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes.
A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles.
A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane and o-anisol to form the corresponding β-hydroxynitroalkane.