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422436

环戊烯-1-羧酸甲酯

Name: 环戊烯-1-羧酸甲酯
Brand: ALDRICH

97%

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关于此项目

线性分子式:

C₅H₇CO₂CH₃

化学文摘社编号:

25662-28-6

分子量:

126.15

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24866432

MDL number:

MFCD00239506

Beilstein/REAXYS Number:

2040162

Assay:

97%

Form:

liquid

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属性

assay

97%

form

liquid

refractive index

n20/D 1.4660 (lit.)

bp

76-78 °C/9 mmHg (lit.)

density

1.031 g/mL at 20 °C (lit.)

functional group

ester

SMILES string

COC(=O)C1=CCCC1

InChI

1S/C7H10O2/c1-9-7(8)6-4-2-3-5-6/h4H,2-3,5H2,1H3

InChI key

VTYCAXIAUKEGBQ-UHFFFAOYSA-N

说明

General description

Methyl 1-cyclopentene-1-carboxylate, a cyclic alkene, is a cyclopentene derivative. It participates in the synthesis of azulene derivatives by initially forming the corresponding cyclopropanol followed by oxy-Cope rearrangement.

Application

Methyl 1-cyclopentene-1-carboxylate may be used as starting material in the synthesis of pinnaic acid and halichlorine. It undergoes asymmetric oxidative Heck reaction with aryl boronic acids to form coupling products in the presence of chiral NHC (N-heterocyclic carbine)-palladium (II) complex.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

143.6 °F - closed cup

flash_point_c

62 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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