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Merck
CN

42254

1-丁基-3-甲基咪唑鎓硫氰酸盐

≥95%

别名:

1-丁基-3-甲基-1H-咪唑鎓硫氰酸盐

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关于此项目

经验公式（希尔记法）:
C9H15N3S
化学文摘社编号:
344790-87-0
分子量:
197.30
NACRES:
NA.22
PubChem Substance ID:
57650105
UNSPSC Code:
12352100
MDL number:
MFCD06798181
Assay:
≥95%
Form:
liquid

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产品名称

1-丁基-3-甲基咪唑鎓硫氰酸盐, ≥95%

InChI

1S/C8H15N2.CHNS/c1-3-4-5-10-7-6-9(2)8-10;2-1-3/h6-8H,3-5H2,1-2H3;3H/q+1;/p-1

SMILES string

[S-]C#N.CCCCn1cc[n+](C)c1

InChI key

SIXHYMZEOJSYQH-UHFFFAOYSA-M

assay

≥95%

form

liquid

impurities

≤1% water

Quality Level

100

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Application

1-Butyl-3-methylimidazolium thiocyanate ([BMIM][SCN]) ionic liquid can be used:
  • As an alternative to conventional entrainers in the extractive distillation of cyclohexane and benzene.
  • In polyethylene oxide-sodium perchlorate electrolyte to increase its ionic conductivity at room temperature.

[BMIM][SCN] show higher degree of solubility of lithium salts such as lithium perchlorate (LiClO4) and N-lithiotrifluoromethanesulfonimide(LiTFSI) when compared to other room temperature ionic liquids due to the presence of polarizable anion (-SCN).

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3

supp_hazards

EUH032

存储类别

10 - Combustible liquids

wgk

WGK 2

flash_point_f

403.7 °F - closed cup

flash_point_c

206.5 °C - closed cup

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCM1495
BCCF6043
BCCD8509
BCBP9467V
BCBM2357V

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Benzene and cyclohexane separation using 1-butyl-3-methylimidazolium thiocyanate
Gonfa G, et al.
AIP Conference Proceedings, 1877(1), 020005-020005 (2017)
Solubility, ionic conductivity and viscosity of lithium salts in room temperature ionic liquids
Rosol ZP, et al.
Green Chemistry, 11(9), 1453-1457 (2009)
Effect of addition of 1-butyl-3-methylimidazolium thiocyanate on conductivity of Na-containing polymer electrolyte
Lee S, et al.
Research on Chemical Intermediates, 43(10), 5403-5411 (2017)
Daisuke Sugioka et al.
Physical chemistry chemical physics : PCCP, 17(19), 13150-13159 (2015-04-29)
Sputtering of noble metals, such as Au, Ag, Pd, and Pt, onto room-temperature ionic liquids (RTILs) enabled the formation of monoparticle films composed of spherical noble metal nanoparticles on the liquid surface only when the RTILs used contained hydroxyl-functionalized cations

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