423424
2-(三甲基硅氧基)-1,3-环己二烯
95%
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关于此项目
经验公式（希尔记法）:
C9H16OSi
化学文摘社编号:
分子量:
168.31
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2079140
Assay:
95%
Form:
liquid
assay
95%
form
liquid
refractive index
n20/D 1.462 (lit.)
bp
65 °C/7 mmHg (lit.)
density
0.899 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C[Si](C)(C)OC1=CCCC=C1
InChI
1S/C9H16OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h5,7-8H,4,6H2,1-3H3
InChI key
WPIRVUXAMPRMAY-UHFFFAOYSA-N
General description
2-(Trimethylsiloxy)-1,3-cyclohexadiene ((cyclohexa-1,5-dien-1-yloxy)trimethylsilane) is silyl enol ether of cyclohexenone. The Diels–Alder reactions with dienophiles α-acetoxyacrylonitrile, acrylonitrile and α-chloroacrylonitrile has been studied.
Application
2-(Trimethylsiloxy)-1,3-cyclohexadiene may be used as a diene in the synthesis of isoquinuclidinone 2-aza[2.2.2]octa-3,5-dione by reacting with p-toluenesulfonyl cyanide.
