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423769

α-乙烯基苯甲醇

97%

别名:

α-乙烯基苯甲醇, α-苯基烯丙基醇, (±)-1-苯基烯丙基醇, 1′-羟基烯丙基苯, 1-羟基-1-苯基-2-丙烯, 1-苯基-2-丙烯-1-醇, 3-苯基-3-羟基-1-丙烯, 苯基乙烯基甲醇

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关于此项目

线性分子式:
C6H5CH(CH=CH2)OH
化学文摘社编号:
42273-76-7
分子量:
134.18
NACRES:
NA.22
PubChem Substance ID:
24866527
UNSPSC Code:
12352100
MDL number:
MFCD00093987
Assay:
97%
Form:
liquid
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Quality Level

200

assay

97%

form

liquid

refractive index

n20/D 1.54 (lit.)

bp

101-102 °C/12 mmHg (lit.)

density

1.021 g/mL at 25 °C (lit.)

functional group

hydroxyl, phenyl

SMILES string

OC(C=C)c1ccccc1

InChI

1S/C9H10O/c1-2-9(10)8-6-4-3-5-7-8/h2-7,9-10H,1H2

InChI key

MHHJQVRGRPHIMR-UHFFFAOYSA-N

General description

α-乙烯基苄醇是一种烯丙醇衍生物。已经报道了使用新型三元催化剂体系催化其异构化反应。 已经报道了使用钨催化的不对称环氧化方法对外消旋α-乙烯基苄醇进行动力学拆分。 已经研究了在RuCl2(PPh3)3 催化剂存在下并且使用In(OAc)3作为共催化剂，α乙烯基苄醇和醛在离子液体中的偶联反应。 已经报道了在二氧化硅固载磺酸（SiO2–SO3H）催化剂催化下，甘油与α-乙烯基苄醇的醚化反应。

Application

α−乙烯基苄醇与醇反应，可合成肉桂基醚。

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

201.2 °F - closed cup

flash_point_c

94 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000331374
0000331375
0000331375
0000331374
0000275150

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Heterogeneously catalyzed etherification of glycerol: new pathways for transformation of glycerol to more valuable chemicals.
Gu Y, et al.
Green Chemistry, 10(2), 164-167 (2008)
Masato Ito et al.
Journal of the American Chemical Society, 127(17), 6172-6173 (2005-04-28)
Highly efficient isomerization of allylic alcohols into saturated carbonyls is accomplished using the catalyst system of Cp*RuCl[Ph2P(CH2)2NH2-kappa2-P,N]-KOt-Bu (Cp* = eta5-C5(CH3)5) under mild conditions. Mechanistic consideration based on isotope-labeling experiments indicated the present reaction is applicable to the asymmetric isomerization of
Chuan Wang et al.
Journal of the American Chemical Society, 136(4), 1222-1225 (2014-01-16)
A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten-bishydroxamic acid complex at room temperature with the use of aqueous 30% H2O2 as oxidant
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全球贸易项目编号

货号GTIN
423769-10G04061837332418
423769-1G04061837332425