产品名称
2-(三氟乙酰基)吡咯, 99%
InChI
1S/C6H4F3NO/c7-6(8,9)5(11)4-2-1-3-10-4/h1-3,10H
SMILES string
FC(F)(F)C(=O)c1ccc[nH]1
InChI key
UMVVPYXSJKIFST-UHFFFAOYSA-N
assay
99%
form
solid
mp
48-50 °C (lit.)
functional group
fluoro
ketone
Quality Level
General description
2-(Trifluoroacetyl)pyrrole, an α,α,α-trifluoromethyl ketone is a 2-substituted pyrrole derivative. It has been synthesized by reacting pyrrole with trifluoroacetic anhydride in benzene at 0°C. Its enantioselective hydrogenation to form corresponding alcohol using 5wt.% Pt/Al2O3 catalyst chirally modified by new synthetic chiral amines has been investigated.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Preparation of Indazoles and Quinazolines by Catalytic Dehydrogenation.
Burnett JrJ and Ainsworth C.
The Journal of Organic Chemistry, 23(9), 1382-1383 (1958)
Chemo and enantioselective hydrogenation of fluorinated ketones on platinum modified with (R)-1-(1-naphthyl) ethylamine derivatives.
Diezi S, et al.
J. Mol. Catal. A: Chem., 239(1), 49-56 (2005)
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