424625
对羟基联苯
purified by sublimation, 99%
别名:
4-羟基联苯
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关于此项目
线性分子式:
C6H5C6H4OH
化学文摘社编号:
分子量:
170.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-179-2
Beilstein/REAXYS Number:
1907452
MDL number:
Assay:
99%
InChI key
YXVFYQXJAXKLAK-UHFFFAOYSA-N
InChI
1S/C12H10O/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,13H
SMILES string
Oc1ccc(cc1)-c2ccccc2
assay
99%
purified by
sublimation
bp
321 °C (lit.)
Quality Level
Gene Information
rat ... Ar(24208)
solubility
water: soluble 0.7 g/L at 20 °C
functional group
phenyl
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General description
4-Phenylphenol (4-hydroxybiphenyl, 4-HBP), a biaryl compound, is a weakly acidic 4-arylphenol. A study on its crystalline structure has been reported. Its rapid, green synthesis via a Pd(0)-catalyzed Suzuki cross-coupling reaction in water has been reported. The standard molar enthalpy of formation of 4-phenylphenol has been evaluated using combustion calorimetry. The solid-matrix luminescence properties for 4-phenylphenol adsorbed on filter paper has been investigated. A study conducted using the yeast two-hybrid assay suggests that it shows estrogenic activity.
Application
4-Phenylphenol may be used in the following studies:
- As a reactant in the synthesis of new azobenzene sulfonic acid dopants by diazotized coupling reaction with sulphanilic acid diazonium salt.
- As a starting material in the synthesis of 2,6-poly(4-phenylphenol).
- As a ligand in the synthesis of aluminum (III) bis(2-methyl-8-quninolinato)-4-phenylphenolate (BAlq).
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1B
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
320.0 °F - closed cup
flash_point_c
160 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Thermochemistry of phenols: experimental standard molar enthalpies of formation of 2-phenylphenol, 4-phenylphenol, 2, 6-diphenylphenol, and 2, 2'-and 4, 4'-dihydroxybiphenyl.
Verevkin SP.
The Journal of Chemical Thermodynamics, 30(3), 389-396 (1998)
" Greening Up" the Suzuki Reaction.
Aktoudianakis E, et al.
Journal of Chemical Education, 85(4), 555-555 (2008)
Preparation of some aryl α-L-arabinofuranosides as substrates for arabino-furanosidase.
Kelly MA, et al.
Carbohydrate Research, 181, 261-266 (1988)
Yuko Ogawa et al.
Food additives and contaminants, 23(4), 422-430 (2006-03-21)
Food contact plastics and rubbers possibly contain many kinds of chemicals such as monomers, oligomers, additives, degradation products of polymers and additives, and impurities. Among them, bisphenol A, nonylphenol, benzylbutyl phthalate, styrene oligomers and hydroxylated benzophenones have been reported to
The polymerization of 4-phenylphenol catalyzed by laccase.
Zhou P and Fu S.
Acta Polymerica Sinica / Gao Fen Zi Xue Bao, 4, 614-616 (2004)
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