425117
2-丁炔酸乙酯
98%
别名:
丁炔酸乙酯
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关于此项目
线性分子式:
CH3C≡CC(O)OCH2CH3
化学文摘社编号:
分子量:
112.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
224-395-6
Beilstein/REAXYS Number:
1744948
MDL number:
产品名称
2-丁炔酸乙酯, 98%
InChI key
FCJJZKCJURDYNF-UHFFFAOYSA-N
InChI
1S/C6H8O2/c1-3-5-6(7)8-4-2/h4H2,1-2H3
SMILES string
CCOC(=O)C#CC
assay
98%
form
liquid
refractive index
n20/D 1.436 (lit.)
bp
160-161 °C/730 mmHg (lit.)
density
0.962 g/mL at 25 °C (lit.)
functional group
ester
Quality Level
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Application
Ethyl 2-butynoate was used in the study of its effect on in vitro degradation and microbial biomass production.
It may be used in the synthesis of the following:
It may be used in the synthesis of the following:
- 3-ethyl, 1-methyl 1-(2-nitrophenyl)-cyclopent-3-ene-1,3-dicarboxylate
- tricyclic aziridine derivatives
- alkenylsilanols
General description
Ethyl 2-butynoate, a 2-alkynoate is a methanogenesis inhibitor. It is an electron deficient internal alkyne that has been reported to undergo codimerization with alkenes to form 1,3-dienes catalyzed by rhodium(I)/H8-BINAP complex. The annulation of thioamides with ethyl 2-butynoate catalyzed by tri-n-butylphosphine to form thiazolines has been investigated.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Dichloro [TADDOLato (2-)-O,O'] titanium/Dichlorobis [1-methylethoxy] titanium-Mediated, Highly Diastereo-and Enantioselective Additions of Silyl Enol Ethers to Nitro Olefins and [3+ 2] Cycloadditions of Primary Adducts to Acetylenes.
Seebach D, et al.
Helvetica Chimica Acta, 82(11), 1829-1842 (1999)
Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols.
Denmark SE and Pan W.
Journal of Organometallic Chemistry, 653(1), 98-104 (2002)
Bing Liu et al.
The Journal of organic chemistry, 67(13), 4595-4598 (2002-06-22)
The annulation of thioamides with 2-alkynoates and 2,3-dienoates under the catalysis of tri-n-butylphosphine was described. The annulation reaction provided a new entry to thiazolines, particularly those with 2-aryl substituents.
Synthesis of 2-azaspiro [4.4] nonan-1-ones via phosphine-catalysed [3+ 2]-cycloadditions.
Yong SR, et al.
Tetrahedron, 61(34), 8120-8129 (2005)
Dariusz Gołowicz et al.
ChemistryOpen, 8(2), 196-200 (2019-03-01)
Low-field benchtop nuclear magnetic resonance (BT-NMR) spectrometers with Halbach magnets are being increasingly used in science and industry as cost-efficient tools for the monitoring of chemical reactions, including hydrogenation. However, their use of low-field magnets limits both resolution and sensitivity.
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