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Merck
CN

427128

三氯化镓

beads, anhydrous, ≥99.999% trace metals basis

别名:

氯化镓

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关于此项目

线性分子式:
GaCl3
化学文摘社编号:
分子量:
176.08
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
236-610-0
MDL number:
Assay:
≥99.999% trace metals basis
Grade:
anhydrous
Form:
beads
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Quality Level

InChI key

UPWPDUACHOATKO-UHFFFAOYSA-K

InChI

1S/3ClH.Ga/h3*1H;/q;;;+3/p-3

SMILES string

Cl[Ga](Cl)Cl

grade

anhydrous

vapor pressure

1 mmHg ( 48 °C)

assay

≥99.999% trace metals basis

form

beads

reaction suitability

reagent type: catalyst
core: gallium

impurities

≤10.0 ppm Trace Metal Analysis

density

2.47 g/mL at 25 °C (lit.)

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General description

在200oC下,通过Ga金属与 Cl2或HCl在N2中反应,可制备氯化镓(III) 。1

Application

用于许多转化反应(例如环氧化物的开环和再环合反应,或者炔烃的三聚反应)的催化剂。

Features and Benefits

使用 GaCl3 和 NaN3 或 Li3N 的低温溶剂热技术可产生纳米晶 GaN。
许多有机键形成反应中的自由基介质和催化剂。

Packaging

样品瓶包装

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chien-Hui Syu et al.
The Science of the total environment, 759, 143943-143943 (2020-12-20)
The emerging contaminants gallium (Ga) and indium (In) are extensively used in advanced industries and are considered as toxic to humans. Limited information is available on the dynamics of Ga and In in soil-upland crop systems. Therefore, this study aimed
Barman, D.C.
Synlett, 2440-2440 (2003)
Tiina Ujula et al.
Molecular imaging and biology : MIB : the official publication of the Academy of Molecular Imaging, 12(3), 259-268 (2009-10-03)
The aim of the study was to compare (68)Ga-chloride with 2-[(18)F]fluoro-2-deoxy-D: -glucose (FDG) for the imaging of pancreatic xenografts. Rats with subcutaneous human pancreatic adenocarcinoma xenografts were evaluated in vivo by dynamic positron emission tomography (PET) and ex vivo by
C Caraco et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 49(12), 1477-1479 (1998-09-24)
Previous studies report that deferoxamine (DFO) binds metallic ions such as Fe3+, In3+ and Ga3+ with very high affinity. This property of DFO has been utilized to label DFO-coupled compounds with radiometals such as 67Ga and 111In. We have studied
Amir R Jalilian et al.
Acta pharmaceutica (Zagreb, Croatia), 59(4), 421-429 (2009-11-19)
beta-Human chorionic gonadotropin (beta-hCG) was successively labeled with [(67)Ga]-gallium chloride after conjugation with freshly prepared diethylenetriaminepentaacetic acid dianhydride (ccDTPA). After solid phase purification of the radiolabeled hormone, high performance liquid chromatography showed radiochemical purity higher than 95 % under optimized

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