方案
98%
表单
liquid
折射率
n20/D 1.426 (lit.)
沸点
170-172 °C (lit.)
密度
0.859 g/mL at 25 °C (lit.)
官能团
amine
isocyanate
储存温度
2-8°C
SMILES字符串
CC(C)(C)CC(C)(C)N=C=O
InChI
1S/C9H17NO/c1-8(2,3)6-9(4,5)10-7-11/h6H2,1-5H3
InChI key
XOHBENIMDRFUIH-UHFFFAOYSA-N
一般描述
1,1,3,3-Tetramethylbutyl isocyanate is a sterically hindered isocyanate. Its synthesis from tert-octylamine has been reported.
应用
1,1,3,3-Tetramethylbutyl isocyanate may be used in the synthesis of amides by Grignard reaction.
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
118.4 °F - closed cup
闪点(°C)
48 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Facile Synthesis of Sterically Hindered and Electron-Deficient Secondary Amides from Isocyanates.
Schafer G, et al.
Angewandte Chemie (International Edition in English), 51(36), 9173-9175 (2012)
Effect of oxidized states of heteroatoms and of orthogonal. pi. systems on radical stabilities.
Luedtke AE and Timberlake JW.
The Journal of Organic Chemistry, 50(2), 268-270 (1985)
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