428469
2,3-二甲基呋喃
99%
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关于此项目
经验公式（希尔记法）:
C6H8O
化学文摘社编号:
分子量:
96.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
2,3-二甲基呋喃, 99%
InChI
1S/C6H8O/c1-5-3-4-7-6(5)2/h3-4H,1-2H3
SMILES string
Cc1ccoc1C
InChI key
FJSKXQVRKZTKSI-UHFFFAOYSA-N
assay
99%
form
liquid
refractive index
n20/D 1.443 (lit.)
bp
42 °C/115 mmHg (lit.)
density
0.91 g/mL at 25 °C (lit.)
Quality Level
Application
2,3-Dimethylfuran may be used in the synthesis of 2,9-dioxabicyclo[3.3.1]nonane.
General description
2,3-Dimethylfuran is a methyl substituted furan. The gas-phase rate constant determined by the relative rate method for the reaction of 2,3-dimethylfuran with NO3 radical was found to be (5.83 ± 0.46)×10-11 and with OH radical was (12.6 ± 0.4)×10-11 (in units of cm3 molecule-1 s-1). It is reported to be formed by the cyclization of (Z)-3-methylpent-2-en-4-yn-1-ol by various methods.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
30.2 °F - closed cup
flash_point_c
-1 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Preparation of 2, 9-dioxabicyclo [3.3.1] nonanes. A model for tirandamycin.
DeShong P, et al.
Tetrahedron Letters, 23(22), 2243-2246 (1982)
Synthesis of a water-soluble carbene complex and its use as catalyst for the synthesis of 2,3-dimethylfuran.
Ozdemir I, et al.
Journal of Organometallic Chemistry, 633(1), 27-32 (2001)
Synthesis and reactivity studies of palladium (ii) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP (=O)(OR)2} Ph2 (R= Et, Ph): application to the catalytic synthesis of 2, 3-dimethylfuran.
Cadierno V, et al.
Dalton Transactions, 47, 5593-5604 (2006)
Palladium-catalyzed cycloisomerization of (Z)-enynols into furans using green solvents: glycerol vs. water.
Francos J and Cadierno V.
Green Chemistry, 12(9), 1552-1555 (2010)
Benzimidazole, Benzothiazole and Benzoxazole Ruthenium (II) Complexes; Catalytic Synthesis of 2,3-Dimethylfuran.
Cetinkaya B, et al.
European Journal of Organic Chemistry, 2000(1), 29-32 (2000)
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