429082
六甲基苯
purified by sublimation, ≥99%
别名:
1,2,3,4,5,6-六甲基苯
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关于此项目
线性分子式:
C6(CH3)6
化学文摘社编号:
分子量:
162.27
Beilstein:
1905834
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
≥99%
纯化方式
sublimation
沸点
264 °C (lit.)
mp
164-166 °C (lit.)
SMILES字符串
Cc1c(C)c(C)c(C)c(C)c1C
InChI
1S/C12H18/c1-7-8(2)10(4)12(6)11(5)9(7)3/h1-6H3
InChI key
YUWFEBAXEOLKSG-UHFFFAOYSA-N
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一般描述
六甲基苯（HMB）是一种甲基苯衍生物。由于两种构型不等价的氢，其在四氯化碳溶液中的泛频光谱显示出双峰结构。在25°C下获得了结晶HMB的溶解热，通过外推法从中推导出了熔化热。甲基的内部运动已通过经验力场计算进行了解释。分析了室温下HMB的偏振拉曼光谱。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
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Hexamethyl(Dewar benzene) (HMDB) was selected to probe the intermediacy of an alkene radical cation during cytochrome P450 (P450) catalyzed epoxidation. P450 catalyzed the allylic oxidation of HMDB exclusively; no rearranged products (indicative of a radical cation intermediate) nor epoxide was
Binyu Lu et al.
Environmental science and pollution research international, 22(12), 9090-9099 (2015-04-16)
Contamination levels and spatial and temporal distributions of six typical synthetic musks (SMs) in water and sediment of the Songhua River in Northeastern China were investigated. Experimental data for 72 water and 52 sediment samples collected at 29 sampling sites
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Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 11(4), 483-488 (2006-04-11)
Ruthenium(II) arene anticancer complexes [(eta6-arene)Ru(en)Cl]PF6 (arene is hexamethylbenzene, p-cymene, indan; en is ethylenediamine) can catalyse regioselective reduction of NAD+ by formate in water to form 1,4-NADH, at pD 7.2, 37 degrees C, and in the presence of air. The catalytic
Detailed features in the local mode overtone bands of ethane, neopentane, tetramethylbutane, and hexamethylbenzene.
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