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线性分子式:
(C6H5)2I+Cl-
化学文摘社编号:
分子量:
316.57
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-049-8
Beilstein/REAXYS Number:
3574977
MDL number:
产品名称
二苯基碘酰氯, ≥98.0% (AT)
InChI key
RSJLWBUYLGJOBD-UHFFFAOYSA-M
InChI
1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1
SMILES string
[Cl-].[I+](c1ccccc1)c2ccccc2
assay
≥98.0% (AT)
reaction suitability
reagent type: oxidant
mp
233-235 °C (subl.) (lit.)
functional group
iodo
Quality Level
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Application
用作以下过程的反应物:
- 铜催化嘌呤与二芳基碘的交叉偶联反应
- 炔芳基硒醚的合成
- 薗头偶联反应制备芳基炔烃
- (芳亚甲基)吲哚的 C-H 官能团化合成
- 苯胺的芳基化
- 可见光光敏系统 - 荧光黄-二(di-Ph 錪鎓)的研究
- 分散光酸直接光解和敏化光解属性的研究
Other Notes
用于亲电苯基化反应(如丙二酸酯和二硫代羧酸酯的反应)的试剂
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Z.-C. Chen et al.
The Journal of Organic Chemistry, 52, 4115-4115 (1987)
The Journal of Organic Chemistry, 4117-4117 (1987)
Synthesis, 723-723 (1988)
Aurélien Bigot et al.
Journal of the American Chemical Society, 133(35), 13778-13781 (2011-08-19)
A new strategy for the catalytic enantioselective α-arylation of N-acyloxazolidinones with chiral copper(II)-bisoxazoline complexes and diaryliodonium salts is described. The mild catalytic conditions are operationally simple, produce valuable synthetic building blocks in excellent yields and enantioselectivities, and can be applied
Sarah A Krawczyk et al.
PloS one, 7(4), e34904-e34904 (2012-04-12)
In obesity, there is an increase in reactive oxygen species (ROS) within adipose tissue caused by increases in inflammation and overnutrition. Hormone sensitive lipase (HSL) is part of the canonical lipolytic pathway and critical for complete lipolysis. This study hypothesizes
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