Merck
CN

43088

Sigma-Aldrich

二苯基碘酰氯

≥98.0% (AT)

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别名:
DPI, NSC 134275
线性分子式:
(C6H5)2I+Cl-
CAS号:
分子量:
316.57
Beilstein:
3574977
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

≥98.0% (AT)

reaction suitability

reagent type: oxidant

mp

233-235 °C (subl.) (lit.)

SMILES string

[Cl-].[I+](c1ccccc1)c2ccccc2

InChI

1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1

InChI key

RSJLWBUYLGJOBD-UHFFFAOYSA-M

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此商品
D2926744514744735
Diphenyliodonium chloride ≥98.0% (AT)

Sigma-Aldrich

43088

二苯基碘酰氯

Diphenyleneiodonium chloride ≥98%

Sigma-Aldrich

D2926

二亚苯基碘鎓氯化物

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

-

reaction suitability

-

mp

233-235 °C (subl.) (lit.)

mp

278 °C

mp

-

mp

-

Quality Level

200

Quality Level

300

Quality Level

100

Quality Level

100

应用

用作以下过程的反应物:
  • 铜催化嘌呤与二芳基碘的交叉偶联反应
  • 炔芳基硒醚的合成
  • 薗头偶联反应制备芳基炔烃
  • (芳亚甲基)吲哚的 C-H 官能团化合成
  • 苯胺的芳基化
  • 可见光光敏系统 - 荧光黄-二(di-Ph 錪鎓)的研究
  • 分散光酸直接光解和敏化光解属性的研究

其他说明

用于亲电苯基化反应(如丙二酸酯和二硫代羧酸酯的反应)的试剂

象形图

Skull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Journal of the American Chemical Society, 133(35), 13778-13781 (2011-08-19)
A new strategy for the catalytic enantioselective α-arylation of N-acyloxazolidinones with chiral copper(II)-bisoxazoline complexes and diaryliodonium salts is described. The mild catalytic conditions are operationally simple, produce valuable synthetic building blocks in excellent yields and enantioselectivities, and can be applied
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Both (-) and (+)-naloxone attenuate inflammation-mediated neurodegeneration by inhibition of microglial activation through superoxide reduction in an opioid receptor-independent manner. Multiple lines of evidence have documented a pivotal role of overactivated NADPH oxidase (NOX2) in inflammation-mediated neurodegeneration. We hypothesized that

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