433063
甲烷亚磺酸钠
technical grade, 85%
别名:
甲烷亚磺酸 钠盐
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关于此项目
线性分子式:
CH3SO2Na
化学文摘社编号:
分子量:
102.09
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
等级
technical grade
方案
85%
mp
222-226 °C (dec.) (lit.)
官能团
sulfinic acid
SMILES字符串
[Na+].CS([O-])=O
InChI
1S/CH4O2S.Na/c1-4(2)3;/h1H3,(H,2,3);/q;+1/p-1
InChI key
LYPGDCWPTHTUDO-UHFFFAOYSA-M
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一般描述
甲磺酸钠是脂肪族亚磺酸钠。已有研究描述了将甲磺酸钠共轭加成到乙烯基杂环化合物中。人们研究了芳基硼酸和甲基亚磺酸钠之间的交叉偶联反应。以甲磺酸为原料，加入一当量的氢氧化钠，稀释至 4M，即可制得原液。
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Jerry J Wu et al.
Journal of hazardous materials, 149(1), 218-225 (2007-05-01)
The present study investigates the oxidation of dimethyl sulfoxide (DMSO) by conventional ozonation and the advanced oxidation processes (AOPs). The major degradation products identified were methanesulfinate, methanesulfonate, formaldehyde, and formic acid in ozonation process. The subsequent degradation of intermediates shows
One-pot synthesis of aryl sulfoxides and sulfonium salts from sulfinic acid as a novel sulfurizing agent.
Yamamoto K, et al.
Chemical Communications (Cambridge, England), 17, 2099-2100 (1996)
C F Babbs et al.
Free radical biology & medicine, 6(5), 493-503 (1989-01-01)
A major impediment to the confirmation of free radical mechanisms in pathogenesis is a lack of direct, chemical evidence that oxygen centered free radicals actually arise in living tissues in quantities sufficient to cause serious damage. This investigation was conducted
Cecilia Arsene et al.
Environmental science & technology, 36(23), 5155-5163 (2003-01-14)
Dimethyl sulfoxide (CH3S(O)CH3: DMSO) is an important product of dimethyl sulfide (CH3SCH3: DMS) photooxidation. The mechanism of the OH-radical initiated oxidation of DMSO is still highly uncertain and a major aim of recent studies has been to establish if methane
Conjugate addition of sodium methanesulfinate to vinyl pyridines and diazines for the synthesis of aliphatic sulfones.
Schaaf GM, et al.
Tetrahedron Letters, 50(17), 1928-1933 (2009)
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