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Merck
CN

433063

甲烷亚磺酸钠

technical grade, 85%

别名:

甲烷亚磺酸 钠盐

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线性分子式:
CH3SO2Na
化学文摘社编号:
分子量:
102.09
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
243-669-6
MDL number:
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产品名称

甲烷亚磺酸钠, technical grade, 85%

InChI key

LYPGDCWPTHTUDO-UHFFFAOYSA-M

InChI

1S/CH4O2S.Na/c1-4(2)3;/h1H3,(H,2,3);/q;+1/p-1

SMILES string

[Na+].CS([O-])=O

grade

technical grade

assay

85%

mp

222-226 °C (dec.) (lit.)

functional group

sulfinic acid

Quality Level

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General description

甲磺酸钠是脂肪族亚磺酸钠。已有研究描述了将甲磺酸钠共轭加成到乙烯基杂环化合物中。人们研究了芳基硼酸和甲基亚磺酸钠之间的交叉偶联反应。以甲磺酸为原料,加入一当量的氢氧化钠,稀释至 4M,即可制得原液。

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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Matthew L Dawson et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(46), 18719-18724 (2012-10-24)
Airborne particles affect human health and significantly influence visibility and climate. A major fraction of these particles result from the reactions of gaseous precursors to generate low-volatility products such as sulfuric acid and high-molecular weight organics that nucleate to form
One-pot synthesis of aryl sulfoxides and sulfonium salts from sulfinic acid as a novel sulfurizing agent.
Yamamoto K, et al.
Chemical Communications (Cambridge, England), 17, 2099-2100 (1996)
Jerry J Wu et al.
Journal of hazardous materials, 149(1), 218-225 (2007-05-01)
The present study investigates the oxidation of dimethyl sulfoxide (DMSO) by conventional ozonation and the advanced oxidation processes (AOPs). The major degradation products identified were methanesulfinate, methanesulfonate, formaldehyde, and formic acid in ozonation process. The subsequent degradation of intermediates shows
S Fukui et al.
Journal of chromatography, 630(1-2), 187-193 (1993-02-05)
For the determination of hydroxyl radicals, dimethyl sulphoxide was used as a molecular probe and the methanesulphinic acid produced was determined by high-performance liquid chromatography of its Fast Yellow GC salt derivative. The results for hydroxyl radicals formed using the
J B Smith et al.
Free radical research communications, 8(2), 101-106 (1990-01-01)
Iron bound to certain chelators is known to promote the conversion of superoxide radicals (O2-) to hydroxyl radicals (HO.) by the superoxide-driven Fenton reaction. The production of HO. by various iron chelates was studied using the reaction of dimethyl sulfoxide

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