433810
(-)-双[(S)-1-苯基乙基]胺
99%
别名:
(-)-双[(S)-α-甲苄基]胺, [S-(R*,R*)]-(-)-双(α-甲苄基)胺
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关于此项目
线性分子式:
[C6H5CH(CH3)]2NH
化学文摘社编号:
分子量:
225.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Assay:
99%
Form:
liquid
InChI
1S/C16H19N/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16/h3-14,17H,1-2H3/t13-,14-/m0/s1
SMILES string
C[C@H](N[C@@H](C)c1ccccc1)c2ccccc2
InChI key
NXLACVVNHYIYJN-KBPBESRZSA-N
assay
99%
form
liquid
optical activity
[α]/D −159°, c = 2 in ethanol
optical purity
ee: ≥99% (GLC)
refractive index
n20/D 1.5525 (lit.)
bp
86 °C/0.05 mmHg (lit.)
density
0.987 g/mL at 25 °C (lit.)
functional group
amine, phenyl
Quality Level
Application
(−)-双[(S)-1-苯基乙基]胺可用作：
- 亚磷酰胺 (Feringa) 配体合成的关键中间产物。
- 新型大环内酯化合物lasonolide A的C(18)-C(24)单元制备的反应剂。
- 他克林−石杉碱甲A杂合体合成的起始材料。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
>235.4 °F - closed cup
flash_point_c
> 113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
(R)-2, 2′-Binaphthoyl-(S, S)-di (1-phenylethyl) aminophosphine. scalable protocols for the syntheses of phosphoramidite (feringa) ligands
Organic Syntheses (2008)
Asymmetric synthesis of the C(18)-C(24) unit of lasonolide A
Nowakowski M and Hoffmann HMR
Tetrahedron Letters, 38(6), 1001-1004 (1997)
Enantioselective synthesis of tacrine-huperzine A hybrids. Preparative chiral MPLC separation of their racemic mixtures and absolute configuration assignments by X-ray diffraction analysis
Camps P, et al.
Tetrahedron Asymmetry, 9(5), 835-849 (1998)
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