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Merck
CN

435503

聚(丙二醇)- 嵌段-聚(乙二醇)- 嵌段-聚(丙二醇)

别名:

Pluronic® 31R1, PPG-PEG-PPG

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化学文摘社编号:
UNSPSC Code:
12352112
PubChem Substance ID:
NACRES:
NA.23
MDL number:
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SMILES string

O2C(C2)C.O1CC1

InChI

1S/C3H6O.C2H4O/c1-3-2-4-3;1-2-3-1/h3H,2H2,1H3;1-2H2

InChI key

RVGRUAULSDPKGF-UHFFFAOYSA-N

form

viscous liquid

Quality Level

composition

PEG, 10 wt. %

refractive index

n20/D 1.454

surface tension

34 dyn/cm, 25 °C, 0.1 wt. % in H2O

viscosity

660 cP(25 °C, Brookfield)(lit.)

transition temp

softening point −25 °C, cloud point 25 °C (1 wt. % aqueous solution)

density

1.018 g/mL at 25 °C

HLB

2.0 - 7.0

General description

聚合物的表面活性取决于 EO/PO 比率。与普朗尼克®表面活性剂相比,PPG-PEG-PPG 表现出较低的起泡性、较大的消泡性和较低的凝胶化倾向。PPG-PEG-PPG 的末端仲羟基与普朗尼克表面活性剂中的伯羟基相比,具有较低的反应活性和酸性。

Application

PPG-PEG-PPG 普朗尼克® 31R1 可作为表面清洗剂(软质和硬质)、涂料中的消泡剂、水处理中,金属加工中的润滑剂,线性和交联聚酯和聚氨酯的消泡剂和填充剂。
软硬表面兼用型清洁剂,涂料和水处理用消泡剂。金属加工润滑剂、消泡助剂以及用于线性和交联聚酯及聚氨酯的扩链剂。

Features and Benefits

表面活性取决于EO/PO比。相比Pluronic®表面活性剂,低起泡、高消泡、更难形成凝胶。端基为二级羟基(二级醇),反应性和酸性低于Pluronic®表面活性剂的一级羟基。

Legal Information

Pluronic is a registered trademark of BASF

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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The block polyethers PEO-PPO-ph-PPO-PEO (BPE) and PPO-PEO-ph-PEO-PPO (BEP) are synthesized by anionic polymerization using bisphenol A as initiator. Compared with Pluronic P123, the aggregation behaviors of BPE and BEP at an air/water interface are investigated by the surface tension and
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