435759
(S)-(+)-香芹酮
96%
别名:
(+)-香芹酮, (S)-5-异丙烯基-2-甲基-2-环己烯酮, 葛缕醇
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关于此项目
经验公式（希尔记法）:
C10H14O
化学文摘社编号:
分子量:
150.22
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
218-827-2
Beilstein/REAXYS Number:
2042970
MDL number:
产品名称
(S)-(+)-香芹酮, 96%
InChI key
ULDHMXUKGWMISQ-VIFPVBQESA-N
InChI
1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m0/s1
SMILES string
CC(=C)[C@H]1CC=C(C)C(=O)C1
assay
96%
form
liquid
optical activity
[α]23/D +55.0±7°, neat
refractive index
n20/D 1.497 (lit.)
bp
96-98 °C/10 mmHg (lit.)
density
0.96 g/mL at 25 °C (lit.)
functional group
ketone
Quality Level
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Application
(S)-(+)-香芹酮可作为起始原料合成：
- (-)-Samaderine Y，一种五环的苦木素类化合物。
- 降龙涎醚[(-)-Ambrox]，一种类萜，是龙涎香香气的主要成分。
- 3β-Acetoxydrimenin（一种倍半萜），通过氰化钾的共轭加成反应继以碱催化的Robinson环化反应制备而成。
- 毒胡萝卜素家族成员，比如trilobolide、nortrilobolide和thapsivillosin F。
General description
( S )-(+)-香芹酮是一种主要存在于香菜和小茴香籽油中的单萜烯，用于化妆品、食品和药物制剂中。
Packaging
( S )-(+)-香芹酮是一种主要存在于香菜和小茴香籽油中的单萜烯，用于化妆品、食品和药物制剂中。
signalword
Warning
hcodes
Hazard Classifications
Skin Sens. 1A
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
204.1 °F - closed cup
flash_point_c
95.6 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
A Route to the Thapsigargins from (S)-Carvone Providing a Substrate-Controlled Total Synthesis of Trilobolide, Nortrilobolide, and Thapsivillosin F
Oliver SF, et al.
Angewandte Chemie (International Edition in English), 42(48), 5996-6000 (2003)
Wladimir J Alonso et al.
Memorias do Instituto Oswaldo Cruz, 98(5), 665-672 (2003-09-16)
The way in which vectors distribute themselves amongst their hosts has important epidemiological consequences. While the role played by active host choice is largely unquestioned, current knowledge relates mostly to the innate response of vectors towards stimuli signalling the presence
Total synthesis of drimane sesquiterpenes from S-(+)-carvone (part 5)
Swarts HJ, et al.
Tetrahedron, 50(33), 10083-10094 (1994)
Total Synthesis of (-)-Samaderine Y from (S)-(+)-Carvone
Shing TKM and Yeung YY
Angewandte Chemie (International Edition in English), 117(48), 8195-8198 (2005)
Total synthesis of (-)-Ambrox from S-(+)-carvone (part 6)
Verstegen-Haaksma AA, et al.
Tetrahedron, 50(33), 10095-10106 (1994)
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