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436372

4,4′-二氨基二苯硫醚

Name: 4,4′-二氨基二苯硫醚
Brand: ALDRICH

98%

别名:

4,4′-硫化二苯胺

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关于此项目

线性分子式:

S(C₆H₄NH₂)₂

化学文摘社编号:

139-65-1

分子量:

216.30

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24867296

EC Number:

205-370-9

Beilstein/REAXYS Number:

1875513

MDL number:

MFCD00025342

Assay:

98%

Form:

solid

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属性

Quality Level

100

assay

98%

form

solid

mp

105-107 °C (lit.)

functional group

thioether

SMILES string

Nc1ccc(Sc2ccc(N)cc2)cc1

InChI

1S/C12H12N2S/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H,13-14H2

InChI key

ICNFHJVPAJKPHW-UHFFFAOYSA-N

说明

General description

4,4′-Diaminodiphenyl sulfide is a diaminodiphenyl analog. On oral administration to rats, it induces haematological and pathological changes indicative of erythrocyte destruction. It has been reported to generate hydrogen peroxide in erythrocytes in vitro. Enzymatic oxidation of 4,4′-diaminodiphenyl sulfide to their sulfoxide derivatives in guinea pig liver homogenates has been reported.

Application

4,4′-Diaminodiphenyl sulfide may be employed for the fabrication of quantum wires and quantum dots by chemical vapor deposition.
It may be used for the preparation of the following:

polypyromellitimides
sulfur-containing copolyimides
polyamides

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pictograms

GHS08,GHS07,GHS09

signalword

Danger

hcodes

H302,H350,H411

pcodes

P202 - P264 - P270 - P273 - P301 + P312 - P308 + P313

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Toxicity of aromatic disulphides. II. Intraerythrocytic hydrogen peroxide formation and oxidative damage by aromatic disulphides.

R Munday

Journal of applied toxicology : JAT, 5(6), 409-413 (1985-12-01)

Diphenyl disulphide has been shown to generate hydrogen peroxide in erythrocytes in vitro. It also induces oxidative damage (reversible and irreversible haemoglobin oxidation, depletion of non-protein and protein-bound thiols) in these cells. Such changes were also recorded in erythrocytes exposed

Polycondensation of pyridine-2,6-dicarboxylic acid with some di-and tetraamino compounds.

Banihashemi A and Eghbali M.

Journal of Polymer Science, 14(11), 2659-2664 (1976)

Toxicity of aromatic disulphides. III. In vivo haemolytic activity of aromatic disulphides.

R Munday et al.

Journal of applied toxicology : JAT, 5(6), 414-417 (1985-12-01)

Diphenyl disulphide, 4,4'-diaminodiphenyl disulphide, 2,2'-diaminodiphenyl disulphide, 4,4'-dimethyldiphenyl disulphide and 4,4'-dinitrodiphenyl disulphide, when administered orally to rats, induced haematological and pathological changes indicative of erythrocyte destruction in vivo. No evidence of haemolysis was detected, however, in animals receiving diphenyl disulphide-2,2'-dicarboxylic acid

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货号	GTIN
436372-25G	04061832115764